TY - JOUR
T1 - Vacuum-UV photofragmentation of polyatomic ions using coincidence techniques
AU - Tuckett, Richard
AU - Jarvis, Gary
AU - Boyle, Kenneth
AU - Mayhew, Christopher
PY - 1999/6/1
Y1 - 1999/6/1
N2 - We describe an apparatus for performing three types of coincidence experiment to study state-selected photofragmentation of polyatomic ions in the gas phase; threshold photoelectron–photoion coincidences (TPEPICO), photoion–fluorescence coincidences (PIFCO), and threshold photoelectron–fluorescence coincidences (TPEFCO). Photoionisation in the vacuum-UV, 10–25 eV, is obtained using tunable radiation from the Daresbury, UK Synchrotron Radiation Source. Examples are taken from published work in CF4+, PCl3+ and PBr3+, and a range of perfluorocarbon cations CxFy+.
AB - We describe an apparatus for performing three types of coincidence experiment to study state-selected photofragmentation of polyatomic ions in the gas phase; threshold photoelectron–photoion coincidences (TPEPICO), photoion–fluorescence coincidences (PIFCO), and threshold photoelectron–fluorescence coincidences (TPEFCO). Photoionisation in the vacuum-UV, 10–25 eV, is obtained using tunable radiation from the Daresbury, UK Synchrotron Radiation Source. Examples are taken from published work in CF4+, PCl3+ and PBr3+, and a range of perfluorocarbon cations CxFy+.
KW - photofragmentation
KW - coincidence experiments
KW - perfluorocarbon cations
U2 - 10.1016/S0368-2048(98)00418-6
DO - 10.1016/S0368-2048(98)00418-6
M3 - Article
SN - 0368-2048
VL - 101-103
SP - 93
EP - 99
JO - Journal of Electron Spectroscopy and Related Phenomena
JF - Journal of Electron Spectroscopy and Related Phenomena
ER -