Synthesis and Structural Characterization of Zn(O₃Pch₂Oh), a New Microporous Zinc Phosphonate

GB Hix; Benson Kariuki; Simon Kitchin; Maryjane Tremayne

doi:10.1021/ic000943x

Synthesis and Structural Characterization of Zn(O₃Pch₂Oh), a New Microporous Zinc Phosphonate

GB Hix, Benson Kariuki, Simon Kitchin, Maryjane Tremayne

Chemistry

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64 Citations (Scopus)

Abstract

Zn(O3PCH2OH) (1) has been formed by reaction of zinc acetate with diethyl hydroxymethylphosphonate. The acidity of the zinc solution effects hydrolysis of the phosphonate to produce phosphonic acid in situ. 1 crystallizes in the trigonal spacegroup R (3) over bar, with a 15.9701(2) Angstrom, c = 7.783(2) Angstrom, and Z = 18. The compound has channels in the [001] direction, formed by phosphonate groups bridging the octahedral coordinated zinc atoms. The zinc atoms are coordinated by the three oxygens of the phosphonate group and the oxygen of the hydroxy group.

Original language	English
Pages (from-to)	1477-1481
Number of pages	5
Journal	Inorganic Chemistry
Volume	40
DOIs	https://doi.org/10.1021/ic000943x
Publication status	Published - 1 Apr 2001

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title = "Synthesis and Structural Characterization of Zn(O₃Pch₂Oh), a New Microporous Zinc Phosphonate",

abstract = "Zn(O3PCH2OH) (1) has been formed by reaction of zinc acetate with diethyl hydroxymethylphosphonate. The acidity of the zinc solution effects hydrolysis of the phosphonate to produce phosphonic acid in situ. 1 crystallizes in the trigonal spacegroup R (3) over bar, with a 15.9701(2) Angstrom, c = 7.783(2) Angstrom, and Z = 18. The compound has channels in the [001] direction, formed by phosphonate groups bridging the octahedral coordinated zinc atoms. The zinc atoms are coordinated by the three oxygens of the phosphonate group and the oxygen of the hydroxy group.",

author = "GB Hix and Benson Kariuki and Simon Kitchin and Maryjane Tremayne",

year = "2001",

month = apr,

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doi = "10.1021/ic000943x",

language = "English",

volume = "40",

pages = "1477--1481",

journal = "Inorganic Chemistry",

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T1 - Synthesis and Structural Characterization of Zn(O₃Pch₂Oh), a New Microporous Zinc Phosphonate

AU - Hix, GB

AU - Kariuki, Benson

AU - Kitchin, Simon

AU - Tremayne, Maryjane

PY - 2001/4/1

Y1 - 2001/4/1

N2 - Zn(O3PCH2OH) (1) has been formed by reaction of zinc acetate with diethyl hydroxymethylphosphonate. The acidity of the zinc solution effects hydrolysis of the phosphonate to produce phosphonic acid in situ. 1 crystallizes in the trigonal spacegroup R (3) over bar, with a 15.9701(2) Angstrom, c = 7.783(2) Angstrom, and Z = 18. The compound has channels in the [001] direction, formed by phosphonate groups bridging the octahedral coordinated zinc atoms. The zinc atoms are coordinated by the three oxygens of the phosphonate group and the oxygen of the hydroxy group.

AB - Zn(O3PCH2OH) (1) has been formed by reaction of zinc acetate with diethyl hydroxymethylphosphonate. The acidity of the zinc solution effects hydrolysis of the phosphonate to produce phosphonic acid in situ. 1 crystallizes in the trigonal spacegroup R (3) over bar, with a 15.9701(2) Angstrom, c = 7.783(2) Angstrom, and Z = 18. The compound has channels in the [001] direction, formed by phosphonate groups bridging the octahedral coordinated zinc atoms. The zinc atoms are coordinated by the three oxygens of the phosphonate group and the oxygen of the hydroxy group.

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U2 - 10.1021/ic000943x

DO - 10.1021/ic000943x

M3 - Article

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SN - 1520-510X

VL - 40

SP - 1477

EP - 1481

JO - Inorganic Chemistry

JF - Inorganic Chemistry

ER -

Synthesis and Structural Characterization of Zn(O₃Pch₂Oh), a New Microporous Zinc Phosphonate

Abstract

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