Synthesis and characterization of trans-Mo(CO)4(p-C 5NH4SO3Na)2

Trino Suárez; Bernardo Fontal; Ghery Zambrano; Marisela Reyes; Fernando Bellandi; Ricardo R. Contreras; Juan C. Diaz; Pedro Cancines; Yuraima Fonseca; Isolda Romero

doi:10.1007/s11144-008-5308-4

Synthesis and characterization of trans-Mo(CO)₄(p-C ₅NH₄SO₃Na)₂

Trino Suárez^*, Bernardo Fontal, Ghery Zambrano, Marisela Reyes, Fernando Bellandi, Ricardo R. Contreras, Juan C. Diaz, Pedro Cancines, Yuraima Fonseca, Isolda Romero

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

Reaction between Mo(CO)₆ and p-C₅NH ₄SO₃Na (1:2 (Mo: p-C₅NH₄SO ₃Na) stoichiometric ratio) gave the trans-Mo(CO)₄(p-C ₅NH₄SO₃Na)₂ complex, (1), in 80% yield. Complex (1) has been characterized by FTIR, ¹H and ¹³C NMR spectroscopy. Complex (1) has most likely an idealized D _4h geometry with trans N-bound p-C₅NH₄SO ₃Na ligands.

Original language	English
Pages (from-to)	21-26
Number of pages	6
Journal	Reaction Kinetics and Catalysis Letters
Volume	94
Issue number	1
DOIs	https://doi.org/10.1007/s11144-008-5308-4
Publication status	Published - 1 Jun 2008
Externally published	Yes

Keywords

Carbonyl complexes
Molybdenum
Pyridine-p-sulphonate

ASJC Scopus subject areas

Catalysis
Physical and Theoretical Chemistry

Access to Document

10.1007/s11144-008-5308-4

Cite this

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title = "Synthesis and characterization of trans-Mo(CO)4(p-C 5NH4SO3Na)2",

abstract = "Reaction between Mo(CO)6 and p-C5NH 4SO3Na (1:2 (Mo: p-C5NH4SO 3Na) stoichiometric ratio) gave the trans-Mo(CO)4(p-C 5NH4SO3Na)2 complex, (1), in 80% yield. Complex (1) has been characterized by FTIR, 1H and 13C NMR spectroscopy. Complex (1) has most likely an idealized D 4h geometry with trans N-bound p-C5NH4SO 3Na ligands.",

keywords = "Carbonyl complexes, Molybdenum, Pyridine-p-sulphonate",

author = "Trino Su{\'a}rez and Bernardo Fontal and Ghery Zambrano and Marisela Reyes and Fernando Bellandi and Contreras, {Ricardo R.} and Diaz, {Juan C.} and Pedro Cancines and Yuraima Fonseca and Isolda Romero",

year = "2008",

month = jun,

day = "1",

doi = "10.1007/s11144-008-5308-4",

language = "English",

volume = "94",

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journal = "Reaction Kinetics and Catalysis Letters",

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TY - JOUR

T1 - Synthesis and characterization of trans-Mo(CO)4(p-C 5NH4SO3Na)2

AU - Suárez, Trino

AU - Fontal, Bernardo

AU - Zambrano, Ghery

AU - Reyes, Marisela

AU - Bellandi, Fernando

AU - Contreras, Ricardo R.

AU - Diaz, Juan C.

AU - Cancines, Pedro

AU - Fonseca, Yuraima

AU - Romero, Isolda

PY - 2008/6/1

Y1 - 2008/6/1

N2 - Reaction between Mo(CO)6 and p-C5NH 4SO3Na (1:2 (Mo: p-C5NH4SO 3Na) stoichiometric ratio) gave the trans-Mo(CO)4(p-C 5NH4SO3Na)2 complex, (1), in 80% yield. Complex (1) has been characterized by FTIR, 1H and 13C NMR spectroscopy. Complex (1) has most likely an idealized D 4h geometry with trans N-bound p-C5NH4SO 3Na ligands.

AB - Reaction between Mo(CO)6 and p-C5NH 4SO3Na (1:2 (Mo: p-C5NH4SO 3Na) stoichiometric ratio) gave the trans-Mo(CO)4(p-C 5NH4SO3Na)2 complex, (1), in 80% yield. Complex (1) has been characterized by FTIR, 1H and 13C NMR spectroscopy. Complex (1) has most likely an idealized D 4h geometry with trans N-bound p-C5NH4SO 3Na ligands.

KW - Carbonyl complexes

KW - Molybdenum

KW - Pyridine-p-sulphonate

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U2 - 10.1007/s11144-008-5308-4

DO - 10.1007/s11144-008-5308-4

M3 - Article

AN - SCOPUS:56049089664

SN - 0133-1736

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SP - 21

EP - 26

JO - Reaction Kinetics and Catalysis Letters

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