Synthesis and characterization of trans-Mo(CO)4(p-C 5NH4SO3Na)2

Trino Suárez, Bernardo Fontal, Ghery Zambrano, Marisela Reyes, Fernando Bellandi, Ricardo R. Contreras, Juan C. Diaz, Pedro Cancines, Yuraima Fonseca, Isolda Romero

Research output: Contribution to journalArticlepeer-review

6 Citations (Scopus)

Abstract

Reaction between Mo(CO)6 and p-C5NH 4SO3Na (1:2 (Mo: p-C5NH4SO 3Na) stoichiometric ratio) gave the trans-Mo(CO)4(p-C 5NH4SO3Na)2 complex, (1), in 80% yield. Complex (1) has been characterized by FTIR, 1H and 13C NMR spectroscopy. Complex (1) has most likely an idealized D 4h geometry with trans N-bound p-C5NH4SO 3Na ligands.

Original languageEnglish
Pages (from-to)21-26
Number of pages6
JournalReaction Kinetics and Catalysis Letters
Volume94
Issue number1
DOIs
Publication statusPublished - 1 Jun 2008
Externally publishedYes

Keywords

  • Carbonyl complexes
  • Molybdenum
  • Pyridine-p-sulphonate

ASJC Scopus subject areas

  • Catalysis
  • Physical and Theoretical Chemistry

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