Abstract
Protonation of a substituted cyclohexadien-1-one (1) leads to the generation of carbocation [3]+, capable of effecting hydride abstraction and oxidation reactions. The molecular structure of [3]+ shows it to be structurally similar to [(p-MeO-C6H4)Ph2C]+. The ability to easily access [3]+ from stable and available precursors, such as 1 and commercially available acids, may allow a wider application of the growing number of trityl-based reactions in organic syntheses.
Original language | English |
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Pages (from-to) | 505-509 |
Journal | The Journal of Organic Chemistry |
Volume | 83 |
Issue number | 1 |
Publication status | Published - 5 Dec 2017 |