Infrared laser spectroscopy of uracil in a pulsed slit jet

Mark R. Viant; Raymond S. Fellers; Ryan P. McLaughlin; Richard J. Saykally

doi:10.1063/1.469960

Infrared laser spectroscopy of uracil in a pulsed slit jet

Mark R. Viant^*, Raymond S. Fellers, Ryan P. McLaughlin, Richard J. Saykally

^*Corresponding author for this work

Biosciences

Research output: Contribution to journal › Article › peer-review

Abstract

A new high-temperature pulsed slit jet source has enabled the first observation of a rotationally resolved vibrational spectrum of a nucleotide base. The spectrum, centered at 1703.888 cm^-1, has been assigned to the fundamental out-of-phase mixed carbonyl stretching vibration of the diketo tautomer of uracil, clarifying an ambiguous assignment from low-resolution studies.

Original language	English
Pages (from-to)	9502-9505
Number of pages	4
Journal	The Journal of Chemical Physics
Volume	103
Issue number	21
DOIs	https://doi.org/10.1063/1.469960
Publication status	Published - 1995

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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@article{7e2311c2e7df4ff1a86dc3af64b418ad,

title = "Infrared laser spectroscopy of uracil in a pulsed slit jet",

abstract = "A new high-temperature pulsed slit jet source has enabled the first observation of a rotationally resolved vibrational spectrum of a nucleotide base. The spectrum, centered at 1703.888 cm-1, has been assigned to the fundamental out-of-phase mixed carbonyl stretching vibration of the diketo tautomer of uracil, clarifying an ambiguous assignment from low-resolution studies.",

author = "Viant, {Mark R.} and Fellers, {Raymond S.} and McLaughlin, {Ryan P.} and Saykally, {Richard J.}",

year = "1995",

doi = "10.1063/1.469960",

language = "English",

volume = "103",

pages = "9502--9505",

journal = "The Journal of Chemical Physics",

issn = "0021-9606",

publisher = "American Institute of Physics",

number = "21",

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T1 - Infrared laser spectroscopy of uracil in a pulsed slit jet

AU - Viant, Mark R.

AU - Fellers, Raymond S.

AU - McLaughlin, Ryan P.

AU - Saykally, Richard J.

PY - 1995

Y1 - 1995

N2 - A new high-temperature pulsed slit jet source has enabled the first observation of a rotationally resolved vibrational spectrum of a nucleotide base. The spectrum, centered at 1703.888 cm-1, has been assigned to the fundamental out-of-phase mixed carbonyl stretching vibration of the diketo tautomer of uracil, clarifying an ambiguous assignment from low-resolution studies.

AB - A new high-temperature pulsed slit jet source has enabled the first observation of a rotationally resolved vibrational spectrum of a nucleotide base. The spectrum, centered at 1703.888 cm-1, has been assigned to the fundamental out-of-phase mixed carbonyl stretching vibration of the diketo tautomer of uracil, clarifying an ambiguous assignment from low-resolution studies.

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U2 - 10.1063/1.469960

DO - 10.1063/1.469960

M3 - Article

AN - SCOPUS:0000365684

SN - 0021-9606

VL - 103

SP - 9502

EP - 9505

JO - The Journal of Chemical Physics

JF - The Journal of Chemical Physics

IS - 21

ER -

Infrared laser spectroscopy of uracil in a pulsed slit jet

Abstract

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