Hydroformylation reactions of the trans-Mo(CO)4(p-C 5NH4SO3NA)2 complex in biphasic medium

Trino Suárez; Bernardo Fontal; Ghery Zambrano; Marisela Reyes; Fernando Bellandi; Ricardo R. Contreras; Juan C. Diaz; Pedro Cancines; Yuraima Fonseca; Isolda Romero

doi:10.1007/s11144-008-5309-3

Hydroformylation reactions of the trans-Mo(CO)₄(p-C ₅NH₄SO₃NA)₂ complex in biphasic medium

Trino Suárez^*, Bernardo Fontal, Ghery Zambrano, Marisela Reyes, Fernando Bellandi, Ricardo R. Contreras, Juan C. Diaz, Pedro Cancines, Yuraima Fonseca, Isolda Romero

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

Trans-bis(sodium pyridine-p-sulphonate)tetracarbonylmolybdenum(0) complex, (trans-Mo(CO)₄(p-PySO₃Na)₂, (1)) was used as a catalytic precursor for the 1-hexene hydroformylation reaction, in biphasic toluene/water medium (T = 100°C, syngas total pressure = 600 psi, pH ₂/pCO = 1). Complex (1) showed good activity favoring the linear aldehyde. Likewise as other organic olefin substrates and with synthetic and real naphtha, good conversions to oxygenated products were obtained.

Original language	English
Pages (from-to)	27-34
Number of pages	8
Journal	Reaction Kinetics and Catalysis Letters
Volume	94
Issue number	1
DOIs	https://doi.org/10.1007/s11144-008-5309-3
Publication status	Published - 1 Jun 2008
Externally published	Yes

Keywords

Biphasic catalysis
Hydroformylation
Molybdenum complex
Naphtha

ASJC Scopus subject areas

Catalysis
Physical and Theoretical Chemistry

Access to Document

10.1007/s11144-008-5309-3

Cite this

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title = "Hydroformylation reactions of the trans-Mo(CO)4(p-C 5NH4SO3NA)2 complex in biphasic medium",

abstract = "Trans-bis(sodium pyridine-p-sulphonate)tetracarbonylmolybdenum(0) complex, (trans-Mo(CO)4(p-PySO3Na)2, (1)) was used as a catalytic precursor for the 1-hexene hydroformylation reaction, in biphasic toluene/water medium (T = 100°C, syngas total pressure = 600 psi, pH 2/pCO = 1). Complex (1) showed good activity favoring the linear aldehyde. Likewise as other organic olefin substrates and with synthetic and real naphtha, good conversions to oxygenated products were obtained.",

keywords = "Biphasic catalysis, Hydroformylation, Molybdenum complex, Naphtha",

author = "Trino Su{\'a}rez and Bernardo Fontal and Ghery Zambrano and Marisela Reyes and Fernando Bellandi and Contreras, {Ricardo R.} and Diaz, {Juan C.} and Pedro Cancines and Yuraima Fonseca and Isolda Romero",

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doi = "10.1007/s11144-008-5309-3",

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journal = "Reaction Kinetics and Catalysis Letters",

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T1 - Hydroformylation reactions of the trans-Mo(CO)4(p-C 5NH4SO3NA)2 complex in biphasic medium

AU - Suárez, Trino

AU - Fontal, Bernardo

AU - Zambrano, Ghery

AU - Reyes, Marisela

AU - Bellandi, Fernando

AU - Contreras, Ricardo R.

AU - Diaz, Juan C.

AU - Cancines, Pedro

AU - Fonseca, Yuraima

AU - Romero, Isolda

PY - 2008/6/1

Y1 - 2008/6/1

N2 - Trans-bis(sodium pyridine-p-sulphonate)tetracarbonylmolybdenum(0) complex, (trans-Mo(CO)4(p-PySO3Na)2, (1)) was used as a catalytic precursor for the 1-hexene hydroformylation reaction, in biphasic toluene/water medium (T = 100°C, syngas total pressure = 600 psi, pH 2/pCO = 1). Complex (1) showed good activity favoring the linear aldehyde. Likewise as other organic olefin substrates and with synthetic and real naphtha, good conversions to oxygenated products were obtained.

AB - Trans-bis(sodium pyridine-p-sulphonate)tetracarbonylmolybdenum(0) complex, (trans-Mo(CO)4(p-PySO3Na)2, (1)) was used as a catalytic precursor for the 1-hexene hydroformylation reaction, in biphasic toluene/water medium (T = 100°C, syngas total pressure = 600 psi, pH 2/pCO = 1). Complex (1) showed good activity favoring the linear aldehyde. Likewise as other organic olefin substrates and with synthetic and real naphtha, good conversions to oxygenated products were obtained.

KW - Biphasic catalysis

KW - Hydroformylation

KW - Molybdenum complex

KW - Naphtha

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SP - 27

EP - 34

JO - Reaction Kinetics and Catalysis Letters

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