Abstract
The solubility of CO2 in the aqueous solutions of 50 mass% 2-Piperidineethanol (2-PPE) and 40 mass% 1-(2-Hydroxyethyl)pyrrolidine (1-(2HE)PRLD) was measured at temperatures from 40 to 120 °C at CO2 loading from 0.04 to 0.8 mol-CO2/mol-amine. The density and viscosity of unloaded and CO2-loaded solutions were measured at temperatures between 20 and 80 °C and fitted to simplified correlations. Based on a thermal degradation test, both solvents were found to be more stable and less corrosive than 30 mass% MEA. However, oxidative degradation tests indicate that the 1-(2HE)PRLD degradation rate is lower than that of 30 mass% MEA while 2-PPE degrades much faster. From the environmental aspect, both solvents are found to be non-toxic and biodegradable in fresh water. These experimental data will be used for estimation of the energetic and environmental potential as solvents for CO2 capture.
Original language | English |
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Pages (from-to) | 260-271 |
Number of pages | 12 |
Journal | International Journal of Greenhouse Gas Control |
Volume | 63 |
Early online date | 15 Jun 2017 |
DOIs | |
Publication status | Published - Aug 2017 |
Keywords
- Degradation
- environmental impact
- Absorption
- CO2 capture
- VLE