A Reactivity Switch in the Gold-Catalysed Coupling of Allyl Sulfides with Propargylic Carboxylates

Paul Davies; SJC Albrecht

doi:10.1055/s-0031-1289866

A Reactivity Switch in the Gold-Catalysed Coupling of Allyl Sulfides with Propargylic Carboxylates

Paul Davies, SJC Albrecht

Chemistry

Research output: Contribution to journal › Article

20 Citations (Scopus)

Abstract

The gold-catalysed coupling of allyl sulfides with propargylic carboxylates follows different pathways depending upon the choice of nonmigrating group on the sulfur and the aromatic group at the propargylic position of the alkyne substrate.

Original language	English
Pages (from-to)	70-73
Number of pages	4
Journal	Synlett
Volume	23
Issue number	1
DOIs	https://doi.org/10.1055/s-0031-1289866
Publication status	Published - 1 Jan 2012

Keywords

sulfur ylides
alkynes
coupling
gold
propargylic carboxylates

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10.1055/s-0031-1289866

Alkynes as "Masked" Ylides. A concept for New Reactions and Reactivity
Davies, P. (Principal Investigator)
Engineering & Physical Science Research Council
1/05/07 → 30/04/09
Project: Research Councils

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title = "A Reactivity Switch in the Gold-Catalysed Coupling of Allyl Sulfides with Propargylic Carboxylates",

abstract = "The gold-catalysed coupling of allyl sulfides with propargylic carboxylates follows different pathways depending upon the choice of nonmigrating group on the sulfur and the aromatic group at the propargylic position of the alkyne substrate.",

keywords = "sulfur ylides, alkynes, coupling, gold, propargylic carboxylates",

author = "Paul Davies and SJC Albrecht",

year = "2012",

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doi = "10.1055/s-0031-1289866",

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AU - Albrecht, SJC

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N2 - The gold-catalysed coupling of allyl sulfides with propargylic carboxylates follows different pathways depending upon the choice of nonmigrating group on the sulfur and the aromatic group at the propargylic position of the alkyne substrate.

AB - The gold-catalysed coupling of allyl sulfides with propargylic carboxylates follows different pathways depending upon the choice of nonmigrating group on the sulfur and the aromatic group at the propargylic position of the alkyne substrate.

KW - sulfur ylides

KW - alkynes

KW - coupling

KW - gold

KW - propargylic carboxylates

U2 - 10.1055/s-0031-1289866

DO - 10.1055/s-0031-1289866

M3 - Article

VL - 23

SP - 70

EP - 73

JO - Synlett

JF - Synlett

IS - 1

ER -

A Reactivity Switch in the Gold-Catalysed Coupling of Allyl Sulfides with Propargylic Carboxylates

Abstract

Keywords

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Projects

Alkynes as "Masked" Ylides. A concept for New Reactions and Reactivity

Cite this