A Kinetic Self-Sorting Approach to Heterocircuit [3]Rotaxanes

Edward A. Neal; Stephen M. Goldup

doi:10.1002/anie.201606640

A Kinetic Self-Sorting Approach to Heterocircuit [3]Rotaxanes

Edward A. Neal, Stephen M. Goldup^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

38 Citations (Scopus)

Abstract

In this proof-of-concept study, an active-template coupling is used to demonstrate a novel kinetic self-sorting process. This process iteratively increases the yield of the target heterocircuit [3]rotaxane product at the expense of other threaded species.

Original language	English
Pages (from-to)	12488-12493
Number of pages	6
Journal	Angewandte Chemie - International Edition
Volume	55
Issue number	40
DOIs	https://doi.org/10.1002/anie.201606640
Publication status	Published - 26 Sept 2016

Bibliographical note

Funding Information:
We thank Fluorochem for the gift of reagents, the Royal Society, EPSRC (Directed Assembly Network; EP/K014382/1) and QMUL for funding. S.M.G. is a Royal Society Research Fellow.

Publisher Copyright:
© 2016 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.

Keywords

active templates
CuAAC
cycloaddition
rotaxanes
self-sorting

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1002/anie.201606640

Cite this

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abstract = "In this proof-of-concept study, an active-template coupling is used to demonstrate a novel kinetic self-sorting process. This process iteratively increases the yield of the target heterocircuit [3]rotaxane product at the expense of other threaded species.",

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A Kinetic Self-Sorting Approach to Heterocircuit [3]Rotaxanes

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

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