Viscosity measurements and modeling of loaded and unloaded aqueous solutions of MDEA, DMEA, DEEA and MAPA

Diego D.D. Pinto; Birgit Johnsen; Muhammad Awais; Hallvard F. Svendsen; Hanna Knuutila

doi:10.1016/j.ces.2017.05.044

Viscosity measurements and modeling of loaded and unloaded aqueous solutions of MDEA, DMEA, DEEA and MAPA

Diego D.D. Pinto, Birgit Johnsen, Muhammad Awais, Hallvard F. Svendsen, Hanna Knuutila^*

^*Corresponding author for this work

Metallurgy and Materials

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

Viscosities of aqueous solutions of 4 amines aimed at CO2 capture by absorption were measured in the temperature range 20–80 °C and for the whole range of compositions. In addition, measurements for loaded solutions up to 1 mol CO2/mole amine for three of the amines systems were also performed. The data were, when possible, compared to literature data and good agreement was found. Both the unloaded and loaded data were modeled using the NRTL-DVIS correlation. The model was able, in both cases, to accurately represent the experimental data except for the 17.9 wt.% MAPA loaded system. The average deviations, calculated as AARD between experimental and predicted values, were for all other cases within 5–6%.

Original language	English
Pages (from-to)	340-350
Number of pages	11
Journal	Chemical Engineering Science
Volume	171
Early online date	29 May 2017
DOIs	https://doi.org/10.1016/j.ces.2017.05.044
Publication status	Published - 2 Nov 2017

Keywords

NRTL-DVISCO2
Amine
Modeling
Viscosity
Capture

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title = "Viscosity measurements and modeling of loaded and unloaded aqueous solutions of MDEA, DMEA, DEEA and MAPA",

abstract = "Viscosities of aqueous solutions of 4 amines aimed at CO2 capture by absorption were measured in the temperature range 20–80 °C and for the whole range of compositions. In addition, measurements for loaded solutions up to 1 mol CO2/mole amine for three of the amines systems were also performed. The data were, when possible, compared to literature data and good agreement was found. Both the unloaded and loaded data were modeled using the NRTL-DVIS correlation. The model was able, in both cases, to accurately represent the experimental data except for the 17.9 wt.% MAPA loaded system. The average deviations, calculated as AARD between experimental and predicted values, were for all other cases within 5–6%.",

keywords = "NRTL-DVISCO2, Amine, Modeling, Viscosity, Capture",

author = "Pinto, {Diego D.D.} and Birgit Johnsen and Muhammad Awais and Svendsen, {Hallvard F.} and Hanna Knuutila",

year = "2017",

month = nov,

day = "2",

doi = "10.1016/j.ces.2017.05.044",

language = "English",

volume = "171",

pages = "340--350",

journal = "Chemical Engineering Science",

issn = "0009-2509",

publisher = "Elsevier",

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TY - JOUR

T1 - Viscosity measurements and modeling of loaded and unloaded aqueous solutions of MDEA, DMEA, DEEA and MAPA

AU - Pinto, Diego D.D.

AU - Johnsen, Birgit

AU - Awais, Muhammad

AU - Svendsen, Hallvard F.

AU - Knuutila, Hanna

PY - 2017/11/2

Y1 - 2017/11/2

N2 - Viscosities of aqueous solutions of 4 amines aimed at CO2 capture by absorption were measured in the temperature range 20–80 °C and for the whole range of compositions. In addition, measurements for loaded solutions up to 1 mol CO2/mole amine for three of the amines systems were also performed. The data were, when possible, compared to literature data and good agreement was found. Both the unloaded and loaded data were modeled using the NRTL-DVIS correlation. The model was able, in both cases, to accurately represent the experimental data except for the 17.9 wt.% MAPA loaded system. The average deviations, calculated as AARD between experimental and predicted values, were for all other cases within 5–6%.

AB - Viscosities of aqueous solutions of 4 amines aimed at CO2 capture by absorption were measured in the temperature range 20–80 °C and for the whole range of compositions. In addition, measurements for loaded solutions up to 1 mol CO2/mole amine for three of the amines systems were also performed. The data were, when possible, compared to literature data and good agreement was found. Both the unloaded and loaded data were modeled using the NRTL-DVIS correlation. The model was able, in both cases, to accurately represent the experimental data except for the 17.9 wt.% MAPA loaded system. The average deviations, calculated as AARD between experimental and predicted values, were for all other cases within 5–6%.

KW - NRTL-DVISCO2

KW - Amine

KW - Modeling

KW - Viscosity

KW - Capture

U2 - 10.1016/j.ces.2017.05.044

DO - 10.1016/j.ces.2017.05.044

M3 - Article

SN - 0009-2509

VL - 171

SP - 340

EP - 350

JO - Chemical Engineering Science

JF - Chemical Engineering Science

ER -

Viscosity measurements and modeling of loaded and unloaded aqueous solutions of MDEA, DMEA, DEEA and MAPA

Abstract

Keywords

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