Abstract
HONO is an important precursor of OH radical and plays a key role in atmospheric chemistry, but its source and formation mechanism remain uncertain, especially during complex atmospheric pollution processes. In this study, HONO mixing ratios were measured by a custom-made instrument during a severe pollution event from 16 to 23 December 2016, at an urban area of Beijing. The measurement was divided into three periods: I (haze), II (severe haze) and III (clean), according to the levels of PM2.5. This pollution episode was characterized by high levels of NO (75 ± 39 and 94 ± 40 ppbV during periods I and II, respectively) and HONO (up to 10.7 ppbV). During the nighttime, the average heterogeneous conversion frequency during the two haze periods were estimated to be 0.0058 and 0.0146 h-1, and it was not the important way to form HONO. Vehicle emissions contributed 52% (± 16)% and 40% (± 18)% to ambient HONO at nighttime during periods I and II. The contribution of homogeneous reaction of NO with OH should be reconsidered under high-NOx conditions and could be noticeable to HONO sources during this pollution event. Furthermore, HONO was positively correlated with PM2.5 during periods I and II, suggesting a potential chemical link between HONO and haze particles.
Original language | English |
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Pages (from-to) | 253-262 |
Number of pages | 10 |
Journal | Science of the Total Environment |
Volume | 648 |
Early online date | 11 Aug 2018 |
DOIs | |
Publication status | Published - 15 Jan 2019 |
Keywords
- Daytime HONO budget
- Haze
- Homogeneous reaction
- Nitrous acid measurement
- Vehicle emissions
ASJC Scopus subject areas
- Environmental Engineering
- Environmental Chemistry
- Waste Management and Disposal
- Pollution