Umbrella motion in aziridines: use of simple chemical inputs to reversibly control the rate of pyramidal inversion
Research output: Contribution to journal › Article
The molecular motion associated with atomic inversion at an aziridine nitrogen can be essentially halted by metal complexation; addition of a second chemical input that decomplexes the metal from the aziridine restores fast inversion (k=40 s(-1) at 303 K).
|Number of pages||1|
|Publication status||Published - 1 Jan 2007|