Tuning coordination chemistry through the second sphere in designed metallocoiled coils

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Tuning coordination chemistry through the second sphere in designed metallocoiled coils. / Slope, Louise N; Hill, Michael G; Smith, Catherine F; Teare, Paul; de Cogan, Felicity J; Britton, Melanie M; Peacock, Anna F A.

In: Chemical communications (Cambridge, England), Vol. 56, No. 26, 04.04.2020, p. 3729-3732.

Research output: Contribution to journalArticlepeer-review

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@article{59b114d243be4ef899b28abdcc6a6de4,
title = "Tuning coordination chemistry through the second sphere in designed metallocoiled coils",
abstract = "The metal hydration state within a designed coiled coil can be progressively tuned across the full integer range (3 → 0 aqua ligands), by careful choice of a second sphere terminal residue, including the lesser used Trp. Potential implications include a four-fold change in MRI relaxivity when applied to lanthanide coiled coils.",
author = "Slope, {Louise N} and Hill, {Michael G} and Smith, {Catherine F} and Paul Teare and {de Cogan}, {Felicity J} and Britton, {Melanie M} and Peacock, {Anna F A}",
year = "2020",
month = apr,
day = "4",
doi = "10.1039/c9cc08189e",
language = "English",
volume = "56",
pages = "3729--3732",
journal = "Chemical Communications ",
issn = "1359-7345",
publisher = "Royal Society of Chemistry",
number = "26",

}

RIS

TY - JOUR

T1 - Tuning coordination chemistry through the second sphere in designed metallocoiled coils

AU - Slope, Louise N

AU - Hill, Michael G

AU - Smith, Catherine F

AU - Teare, Paul

AU - de Cogan, Felicity J

AU - Britton, Melanie M

AU - Peacock, Anna F A

PY - 2020/4/4

Y1 - 2020/4/4

N2 - The metal hydration state within a designed coiled coil can be progressively tuned across the full integer range (3 → 0 aqua ligands), by careful choice of a second sphere terminal residue, including the lesser used Trp. Potential implications include a four-fold change in MRI relaxivity when applied to lanthanide coiled coils.

AB - The metal hydration state within a designed coiled coil can be progressively tuned across the full integer range (3 → 0 aqua ligands), by careful choice of a second sphere terminal residue, including the lesser used Trp. Potential implications include a four-fold change in MRI relaxivity when applied to lanthanide coiled coils.

U2 - 10.1039/c9cc08189e

DO - 10.1039/c9cc08189e

M3 - Article

C2 - 32129331

VL - 56

SP - 3729

EP - 3732

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 26

ER -