Total Synthesis and Structural Revision of a Mangrove Alkaloid

Michael Green; Gary Peczkowski; Aneesa Al-Ani; Sophie Benjamin; Nigel Simpkins; Alan M Jones

doi:10.1039/C7RA10483A

Total Synthesis and Structural Revision of a Mangrove Alkaloid

Michael Green, Gary Peczkowski, Aneesa Al-Ani, Sophie Benjamin, Nigel Simpkins, Alan M Jones

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3 Citations (Scopus)

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Abstract

We report the total synthesis of an alkaloid isolated from the mangrove fungi Hypocrea virens, based on the originally claimed structure, via a photochemical sequence. Inconsistencies between data sets led to a revision of the proposed structure followed by a concise synthetic sequence to deliver the revised natural product.

Original language	English
Pages (from-to)	48754-48758
Number of pages	5
Journal	RSC Advances
Volume	7
Issue number	77
Early online date	17 Oct 2017
DOIs	https://doi.org/10.1039/C7RA10483A
Publication status	E-pub ahead of print - 17 Oct 2017

ASJC Scopus subject areas

Chemistry(all)
Chemical Engineering(all)

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Green_et_al_Total_synthesis_and_structural_revision_RSC_AdvancesFinal published version, 769 KBLicence: Creative Commons: Attribution (CC BY)

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title = "Total Synthesis and Structural Revision of a Mangrove Alkaloid",

abstract = "We report the total synthesis of an alkaloid isolated from the mangrove fungi Hypocrea virens, based on the originally claimed structure, via a photochemical sequence. Inconsistencies between data sets led to a revision of the proposed structure followed by a concise synthetic sequence to deliver the revised natural product.",

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AU - Peczkowski, Gary

AU - Al-Ani, Aneesa

AU - Benjamin, Sophie

AU - Simpkins, Nigel

AU - Jones, Alan M

PY - 2017/10/17

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AB - We report the total synthesis of an alkaloid isolated from the mangrove fungi Hypocrea virens, based on the originally claimed structure, via a photochemical sequence. Inconsistencies between data sets led to a revision of the proposed structure followed by a concise synthetic sequence to deliver the revised natural product.

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DO - 10.1039/C7RA10483A

M3 - Article

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JO - RSC Advances

JF - RSC Advances

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Total Synthesis and Structural Revision of a Mangrove Alkaloid

Abstract

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