Thionated perylene diimides with intense absorbance in the near-IR

B.A. Llewellyn; C.R. Pfeiffer; W. Lewis; N.R. Champness

doi:10.1039/c5cc09962e

Thionated perylene diimides with intense absorbance in the near-IR

B.A. Llewellyn, C.R. Pfeiffer, W. Lewis, N.R. Champness

Chemistry

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

A synthetic strategy involving a combination of tetra-thionation and amine substitution in the bay region of a perylene diimide (PDI) leads to remarkable examples of neutral PDIs with intense absorption maxima in the near infrared. Generation of the corresponding monoanions red shifts the absorption profile to give short-wavelength infrared bands.

Original language	English
Pages (from-to)	2099-2102
Journal	Chemical Communications
Volume	52
Issue number	10
Early online date	15 Dec 2015
DOIs	https://doi.org/10.1039/c5cc09962e
Publication status	Published - 4 Feb 2016

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abstract = "A synthetic strategy involving a combination of tetra-thionation and amine substitution in the bay region of a perylene diimide (PDI) leads to remarkable examples of neutral PDIs with intense absorption maxima in the near infrared. Generation of the corresponding monoanions red shifts the absorption profile to give short-wavelength infrared bands.",

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AU - Lewis, W.

AU - Champness, N.R.

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AB - A synthetic strategy involving a combination of tetra-thionation and amine substitution in the bay region of a perylene diimide (PDI) leads to remarkable examples of neutral PDIs with intense absorption maxima in the near infrared. Generation of the corresponding monoanions red shifts the absorption profile to give short-wavelength infrared bands.

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Thionated perylene diimides with intense absorbance in the near-IR

Abstract

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