Synthesis of the first lanthanide complexes of dialkyl α-hydroxyiminophosphonates; ambivalent ligand bonding in the PrIII and NdIII complexes of diisopropyl α-hydroxyiminopropylphosphonate (L1), [PrL1 3Cl3] and [NdL1 2(NO3)3(H2O)]

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@article{1d11c7ef7ab54d73923f5013330f6591,
title = "Synthesis of the first lanthanide complexes of dialkyl α-hydroxyiminophosphonates; ambivalent ligand bonding in the PrIII and NdIII complexes of diisopropyl α-hydroxyiminopropylphosphonate (L1), [PrL1 3Cl3] and [NdL1 2(NO3)3(H2O)]",
abstract = "Lanthanide complexes of dialkyl α-hydroxyiminophosphonates (RO)2P(O)C(R′)N(OH) (L1-L3), where R = Et or Pri and R′ = Me or Et, have been prepared for the first time; the crystal structures of two complexes of L1 (R = Pri, R′ = Et) have been determined, showing nine-co-ordination geometry in both cases with asymmetric bidentate ligands in [PrL3 1Cl3] and monodentate bonding in [NdL2 1(NO3)3(H2O)] demonstrating that the ambivalent nature of the new ligands allow formation of neutral complexes.",
author = "Bligh, {S. W Annie} and Nick Choi and Hudson, {Harry R.} and McGrath, {Catherine Mary} and Mary McPartlin",
year = "1994",
doi = "10.1039/DT9940002335",
language = "English",
pages = "2335--2337",
journal = "Journal of the Chemical Society, Dalton Transactions",
issn = "1472-7773",
publisher = "Royal Society of Chemistry",
number = "15",

}

RIS

TY - JOUR

T1 - Synthesis of the first lanthanide complexes of dialkyl α-hydroxyiminophosphonates; ambivalent ligand bonding in the PrIII and NdIII complexes of diisopropyl α-hydroxyiminopropylphosphonate (L1), [PrL1 3Cl3] and [NdL1 2(NO3)3(H2O)]

AU - Bligh, S. W Annie

AU - Choi, Nick

AU - Hudson, Harry R.

AU - McGrath, Catherine Mary

AU - McPartlin, Mary

PY - 1994

Y1 - 1994

N2 - Lanthanide complexes of dialkyl α-hydroxyiminophosphonates (RO)2P(O)C(R′)N(OH) (L1-L3), where R = Et or Pri and R′ = Me or Et, have been prepared for the first time; the crystal structures of two complexes of L1 (R = Pri, R′ = Et) have been determined, showing nine-co-ordination geometry in both cases with asymmetric bidentate ligands in [PrL3 1Cl3] and monodentate bonding in [NdL2 1(NO3)3(H2O)] demonstrating that the ambivalent nature of the new ligands allow formation of neutral complexes.

AB - Lanthanide complexes of dialkyl α-hydroxyiminophosphonates (RO)2P(O)C(R′)N(OH) (L1-L3), where R = Et or Pri and R′ = Me or Et, have been prepared for the first time; the crystal structures of two complexes of L1 (R = Pri, R′ = Et) have been determined, showing nine-co-ordination geometry in both cases with asymmetric bidentate ligands in [PrL3 1Cl3] and monodentate bonding in [NdL2 1(NO3)3(H2O)] demonstrating that the ambivalent nature of the new ligands allow formation of neutral complexes.

UR - http://www.scopus.com/inward/record.url?scp=37049072027&partnerID=8YFLogxK

U2 - 10.1039/DT9940002335

DO - 10.1039/DT9940002335

M3 - Article

AN - SCOPUS:37049072027

SP - 2335

EP - 2337

JO - Journal of the Chemical Society, Dalton Transactions

JF - Journal of the Chemical Society, Dalton Transactions

SN - 1472-7773

IS - 15

ER -