Synthesis of the first completely spin-compatible N@C60 cyclopropane derivatives by carefully tuning the DBU base catalyst

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Abstract

Two cyclopropane derivatives of N@C60 were synthesised by well-controlled Bingel reactions, in which 94% of the spin centres were retained, as confirmed by a series of quantitative electron spin paramagnetic resonance (EPR) measurements. Further study on the influence of the DBU catalyst base revealed a spin loss mechanism through a fullerene–DBU diradical.

Details

Original languageEnglish
Pages (from-to)7096-7099
Number of pages4
JournalChemical Communications
Volume51
Publication statusPublished - 18 Mar 2015