Synthesis and structural determination of the new oxide fluoride BaFeO2F

R Heap; PR Slater; FJ Berry; O Helgason; Adrian Wright

doi:10.1016/j.ssc.2006.11.037

Synthesis and structural determination of the new oxide fluoride BaFeO2F

R Heap, PR Slater, FJ Berry, O Helgason, Adrian Wright

Chemistry

Research output: Contribution to journal › Article

46 Citations (Scopus)

Abstract

Low temperature fluorination of BaFeO3-x, using poly(vinylidene fluoride) leads to the formation of the oxide fluoride BaFeO2F. Mossbauer spectroscopy shows that this phase exhibits magnetic ordering at room temperature due to interactions between the Fe3+ ions, with an ordering temperature of 645 (+/- 5) K. Neutron diffraction studies show that the phase has cubic symmetry and confirm the presence of magnetic ordering (G-type antiferromagnetic) at room temperature. (c) 2006 Elsevier Ltd. All rights reserved.

Original language	English
Pages (from-to)	467-470
Number of pages	4
Journal	Solid State Communications
Volume	141
Issue number	8
DOIs	https://doi.org/10.1016/j.ssc.2006.11.037
Publication status	Published - 1 Feb 2007

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title = "Synthesis and structural determination of the new oxide fluoride BaFeO2F",

abstract = "Low temperature fluorination of BaFeO3-x, using poly(vinylidene fluoride) leads to the formation of the oxide fluoride BaFeO2F. Mossbauer spectroscopy shows that this phase exhibits magnetic ordering at room temperature due to interactions between the Fe3+ ions, with an ordering temperature of 645 (+/- 5) K. Neutron diffraction studies show that the phase has cubic symmetry and confirm the presence of magnetic ordering (G-type antiferromagnetic) at room temperature. (c) 2006 Elsevier Ltd. All rights reserved.",

author = "R Heap and PR Slater and FJ Berry and O Helgason and Adrian Wright",

year = "2007",

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T1 - Synthesis and structural determination of the new oxide fluoride BaFeO2F

AU - Heap, R

AU - Slater, PR

AU - Berry, FJ

AU - Helgason, O

AU - Wright, Adrian

PY - 2007/2/1

Y1 - 2007/2/1

N2 - Low temperature fluorination of BaFeO3-x, using poly(vinylidene fluoride) leads to the formation of the oxide fluoride BaFeO2F. Mossbauer spectroscopy shows that this phase exhibits magnetic ordering at room temperature due to interactions between the Fe3+ ions, with an ordering temperature of 645 (+/- 5) K. Neutron diffraction studies show that the phase has cubic symmetry and confirm the presence of magnetic ordering (G-type antiferromagnetic) at room temperature. (c) 2006 Elsevier Ltd. All rights reserved.

AB - Low temperature fluorination of BaFeO3-x, using poly(vinylidene fluoride) leads to the formation of the oxide fluoride BaFeO2F. Mossbauer spectroscopy shows that this phase exhibits magnetic ordering at room temperature due to interactions between the Fe3+ ions, with an ordering temperature of 645 (+/- 5) K. Neutron diffraction studies show that the phase has cubic symmetry and confirm the presence of magnetic ordering (G-type antiferromagnetic) at room temperature. (c) 2006 Elsevier Ltd. All rights reserved.

U2 - 10.1016/j.ssc.2006.11.037

DO - 10.1016/j.ssc.2006.11.037

M3 - Article

VL - 141

SP - 467

EP - 470

JO - Solid State Communications

JF - Solid State Communications

IS - 8

ER -

Synthesis and structural determination of the new oxide fluoride BaFeO2F

Abstract

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