Synthesis and Structural Characterization of Zn(O₃Pch₂Oh), a New Microporous Zinc Phosphonate

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@article{8484d780f62c4ea393ad3f6b92d4e5f0,
title = "Synthesis and Structural Characterization of Zn(O₃Pch₂Oh), a New Microporous Zinc Phosphonate",
abstract = "Zn(O3PCH2OH) (1) has been formed by reaction of zinc acetate with diethyl hydroxymethylphosphonate. The acidity of the zinc solution effects hydrolysis of the phosphonate to produce phosphonic acid in situ. 1 crystallizes in the trigonal spacegroup R (3) over bar, with a 15.9701(2) Angstrom, c = 7.783(2) Angstrom, and Z = 18. The compound has channels in the [001] direction, formed by phosphonate groups bridging the octahedral coordinated zinc atoms. The zinc atoms are coordinated by the three oxygens of the phosphonate group and the oxygen of the hydroxy group.",
author = "GB Hix and Benson Kariuki and Simon Kitchin and Maryjane Tremayne",
year = "2001",
month = apr,
day = "1",
doi = "10.1021/ic000943x",
language = "English",
volume = "40",
pages = "1477--1481",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "American Chemical Society",

}

RIS

TY - JOUR

T1 - Synthesis and Structural Characterization of Zn(O₃Pch₂Oh), a New Microporous Zinc Phosphonate

AU - Hix, GB

AU - Kariuki, Benson

AU - Kitchin, Simon

AU - Tremayne, Maryjane

PY - 2001/4/1

Y1 - 2001/4/1

N2 - Zn(O3PCH2OH) (1) has been formed by reaction of zinc acetate with diethyl hydroxymethylphosphonate. The acidity of the zinc solution effects hydrolysis of the phosphonate to produce phosphonic acid in situ. 1 crystallizes in the trigonal spacegroup R (3) over bar, with a 15.9701(2) Angstrom, c = 7.783(2) Angstrom, and Z = 18. The compound has channels in the [001] direction, formed by phosphonate groups bridging the octahedral coordinated zinc atoms. The zinc atoms are coordinated by the three oxygens of the phosphonate group and the oxygen of the hydroxy group.

AB - Zn(O3PCH2OH) (1) has been formed by reaction of zinc acetate with diethyl hydroxymethylphosphonate. The acidity of the zinc solution effects hydrolysis of the phosphonate to produce phosphonic acid in situ. 1 crystallizes in the trigonal spacegroup R (3) over bar, with a 15.9701(2) Angstrom, c = 7.783(2) Angstrom, and Z = 18. The compound has channels in the [001] direction, formed by phosphonate groups bridging the octahedral coordinated zinc atoms. The zinc atoms are coordinated by the three oxygens of the phosphonate group and the oxygen of the hydroxy group.

UR - http://www.scopus.com/inward/record.url?scp=0035952503&partnerID=8YFLogxK

U2 - 10.1021/ic000943x

DO - 10.1021/ic000943x

M3 - Article

C2 - 11261953

VL - 40

SP - 1477

EP - 1481

JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

ER -