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Abstract
A method for probing the strength of B-N dative bonds is reported. The activation parameters for nitrogen inversion in a series of azetidines tethered to boronate esters have been quantified by VT-NMR and the measured barriers correlated with data obtained by (11)B NMR, X-ray crystallography and MP2 calculations.
Original language | English |
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Pages (from-to) | 2509-11 |
Number of pages | 3 |
Journal | Chemical Communications |
Volume | 49 |
Issue number | 25 |
DOIs | |
Publication status | Published - 28 Mar 2013 |
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Dive into the research topics of 'Study of boron-nitrogen dative bonds using azetidine inversion dynamics.'. Together they form a unique fingerprint.Projects
- 1 Finished
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Controlling the Molecular Motion Associated with Pyramidal Inversion : Towards New Types of Nanoscale Switches
Engineering & Physical Science Research Council
1/04/08 → 31/12/10
Project: Research Councils