Source apportionment of particle number size distribution in urban background and traffic stations in four European cities

Research output: Contribution to journalArticle

Authors

  • Ioar Rivas
  • Fulvio Amato
  • David C. Green
  • Leena Jarvi
  • Christoph Hueglin
  • Cristina Reche
  • Hilkka Timonen
  • Gary W. Fuller
  • Jarkko V. Niemi
  • Noemi Perez
  • Minna Aurela
  • Philip K. Hopke
  • Andres Alastuey
  • Markku Kulmala
  • Xavier Querol
  • Frank J. Kelly

Colleges, School and Institutes

External organisations

  • Department of Environmental Sciences/Center of Excellence in Environmental Studies, King Abdulaziz University
  • Ioar Rivas
  • MRC-PHE Centre for Environment and Health, Environmental Research Group, King's College London, 150 Stamford Street, London SE1 9NH
  • Institute of Atmospheric and Earth System Sciences / Physics, Faculty of Science, P.O. Box 64, FI-00014 University of Helsinki, Finland
  • Laboratory for Air Pollution and Environmental Technology, Swiss Federal Laboratories for Materials Science and Technology (EMPA), Dübendorf, Switzerland
  • Atmospheric Composition Research, Finnish Meteorological Institute, P.O. Box 503, FI-00101 Helsinki, Finland
  • Center for Air Resources Engineering and Science, Clarkson University, Potsdam, NY 13699, USA
  • Institute of Environmental Assessment and Water Research, Spanish Research Council (IDÆA-CSIC)
  • Spanish Research Council (IDÆA-CSIC)
  • Finnish Meteorological Institute
  • Helsinki Region Environmental Services Authority, FI-00240 Helsinki, Finland
  • Helsinki Region Environmental Services Authority
  • Institute of Environmental Assessment and Water Research (IDAEA-CSIC), C/Jordi Girona 18-26, Barcelona, 08034, Spain
  • Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, Helsinki, Finland
  • University of Helsinki
  • Institute of Environmental Assessment and Water Research (IDAEA-CSIC)
  • MRC-PHE Centre for Environment and Health
  • King's College London

Abstract

Ultrafine particles (UFP) are suspected of having significant impacts on health. However, there have only been a limited number of studies on sources of UFP compared to larger particles. In this work, we identified and quantified the sources and processes contributing to particle number size distributions (PNSD) using Positive Matrix Factorization (PMF) at six monitoring stations (four urban background and two street canyon) from four European cities: Barcelona, Helsinki, London, and Zurich. These cities are characterised by different meteorological conditions and emissions. The common sources across all stations were Photonucleation, traffic emissions (3 sources, from fresh to aged emissions: Traffic nucleation, Fresh traffic – mode diameter between 13-37 nm, and Urban – mode diameter between 44-81 nm, mainly traffic but influenced by other sources in some cities), and Secondary particles. The Photonucleation factor was only directly identified by PMF for Barcelona, while an additional split of the Nucleation factor (into Photonucleation and Traffic nucleation) by using NOx concentrations as a proxy for traffic emissions was performed for all other stations. The sum of all traffic sources resulted in a maximum relative contributions ranging from 71 to 94 % (annual average) thereby being the main contributor at all stations. In London and Zurich, the relative contribution of the sources did not vary significantly between seasons. In contrast, the high levels of solar radiation in Barcelona led to an important contribution of Photonucleation particles (ranging from 14% during the winter period to 35% during summer). Biogenic emissions were a source identified only in Helsinki (both in the urban background and street canyon stations), that contributed importantly during summer (23 % in urban background). Airport emissions contributed to Nucleation particles at urban background sites, as the highest concentrations of this source took place when the wind was blowing from the airport direction in all cities.

Details

Original languageEnglish
Pages (from-to)105345
JournalEnvironment International
Volume135
Publication statusPublished - 2020

Keywords

  • Positive Matrix Factorization, Ultrafine particles, Particle number size distributions, Photonucleation, Traffic emissions; Airport emissions