Redox-activity in complexes with Mo(NO) and Mo(O) cores: facts and consequences

JA McCleverty; MD Ward; Christopher Jones

doi:10.1080/02603590108050873

Redox-activity in complexes with Mo(NO) and Mo(O) cores: facts and consequences

JA McCleverty, MD Ward, Christopher Jones

Chemistry

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13 Citations (Scopus)

Abstract

A series of mono, di-, tri- and tetranuclear nitrosyl and oxo molybdenum complexes containing the tris(3,5-dimethylpyrazolyl)borato ligand exhibit a range of redox processes which are controlled mainly by the ligands and by the extent of oligonucleation. Homo- and hetero-dinuclear complexes have a range of properties dependent on this redox behaviour, and linear (electrochromism in the near infrared) and non-linear (second harmonic generation) properties are described.

Original language	English
Pages (from-to)	293-326
Number of pages	34
Journal	Comments on Inorganic Chemistry
Volume	22
Issue number	5
DOIs	https://doi.org/10.1080/02603590108050873
Publication status	Published - 1 Jan 2001

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abstract = "A series of mono, di-, tri- and tetranuclear nitrosyl and oxo molybdenum complexes containing the tris(3,5-dimethylpyrazolyl)borato ligand exhibit a range of redox processes which are controlled mainly by the ligands and by the extent of oligonucleation. Homo- and hetero-dinuclear complexes have a range of properties dependent on this redox behaviour, and linear (electrochromism in the near infrared) and non-linear (second harmonic generation) properties are described.",

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N2 - A series of mono, di-, tri- and tetranuclear nitrosyl and oxo molybdenum complexes containing the tris(3,5-dimethylpyrazolyl)borato ligand exhibit a range of redox processes which are controlled mainly by the ligands and by the extent of oligonucleation. Homo- and hetero-dinuclear complexes have a range of properties dependent on this redox behaviour, and linear (electrochromism in the near infrared) and non-linear (second harmonic generation) properties are described.

AB - A series of mono, di-, tri- and tetranuclear nitrosyl and oxo molybdenum complexes containing the tris(3,5-dimethylpyrazolyl)borato ligand exhibit a range of redox processes which are controlled mainly by the ligands and by the extent of oligonucleation. Homo- and hetero-dinuclear complexes have a range of properties dependent on this redox behaviour, and linear (electrochromism in the near infrared) and non-linear (second harmonic generation) properties are described.

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DO - 10.1080/02603590108050873

M3 - Article

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EP - 326

JO - Comments on Inorganic Chemistry

JF - Comments on Inorganic Chemistry

IS - 5

ER -

Redox-activity in complexes with Mo(NO) and Mo(O) cores: facts and consequences

Abstract

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