Redistribution of terpy ligands - approaches to new dynamic combinatorial libraries

Research output: Contribution to journalArticle

Authors

  • T Kulke
  • C Lazzarini
  • ER Schofield
  • Y Zimmermann

Colleges, School and Institutes

Abstract

Mixing solutions of homoleptic cobalt(II) complexes [CoA(2)](2+) and [CoB2](2+) results in the establishment of a combinatorial library containing the heteroleptic complex [CoAB](2+) By using enantiomorphic ligands A and B the reactions may be followed by H-1 NMR spectroscopy. Exchange reactions with 6-substituted ligands are slower than those with 5- and 4-substituted species.

Details

Original languageEnglish
Pages (from-to)2864-2871
Number of pages8
JournalJournal of the Chemical Society. Dalton Transactions
Issue number19
Publication statusPublished - 1 Oct 2001