Redistribution of terpy ligands - approaches to new dynamic combinatorial libraries

Edwin Constable; Catherine Housecroft; T Kulke; C Lazzarini; ER Schofield; Y Zimmermann

Redistribution of terpy ligands - approaches to new dynamic combinatorial libraries

Edwin Constable, Catherine Housecroft, T Kulke, C Lazzarini, ER Schofield, Y Zimmermann

Chemistry

Research output: Contribution to journal › Article

71 Citations (Scopus)

Abstract

Mixing solutions of homoleptic cobalt(II) complexes [CoA(2)](2+) and [CoB2](2+) results in the establishment of a combinatorial library containing the heteroleptic complex [CoAB](2+) By using enantiomorphic ligands A and B the reactions may be followed by H-1 NMR spectroscopy. Exchange reactions with 6-substituted ligands are slower than those with 5- and 4-substituted species.

Original language	English
Pages (from-to)	2864-2871
Number of pages	8
Journal	Journal of the Chemical Society. Dalton Transactions
Issue number	19
Publication status	Published - 1 Oct 2001

Cite this

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title = "Redistribution of terpy ligands - approaches to new dynamic combinatorial libraries",

abstract = "Mixing solutions of homoleptic cobalt(II) complexes [CoA(2)](2+) and [CoB2](2+) results in the establishment of a combinatorial library containing the heteroleptic complex [CoAB](2+) By using enantiomorphic ligands A and B the reactions may be followed by H-1 NMR spectroscopy. Exchange reactions with 6-substituted ligands are slower than those with 5- and 4-substituted species.",

author = "Edwin Constable and Catherine Housecroft and T Kulke and C Lazzarini and ER Schofield and Y Zimmermann",

year = "2001",

month = oct,

day = "1",

language = "English",

pages = "2864--2871",

journal = "Journal of the Chemical Society. Dalton Transactions",

publisher = "Royal Society of Chemistry",

number = "19",

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TY - JOUR

T1 - Redistribution of terpy ligands - approaches to new dynamic combinatorial libraries

AU - Constable, Edwin

AU - Housecroft, Catherine

AU - Kulke, T

AU - Lazzarini, C

AU - Schofield, ER

AU - Zimmermann, Y

PY - 2001/10/1

Y1 - 2001/10/1

N2 - Mixing solutions of homoleptic cobalt(II) complexes [CoA(2)](2+) and [CoB2](2+) results in the establishment of a combinatorial library containing the heteroleptic complex [CoAB](2+) By using enantiomorphic ligands A and B the reactions may be followed by H-1 NMR spectroscopy. Exchange reactions with 6-substituted ligands are slower than those with 5- and 4-substituted species.

AB - Mixing solutions of homoleptic cobalt(II) complexes [CoA(2)](2+) and [CoB2](2+) results in the establishment of a combinatorial library containing the heteroleptic complex [CoAB](2+) By using enantiomorphic ligands A and B the reactions may be followed by H-1 NMR spectroscopy. Exchange reactions with 6-substituted ligands are slower than those with 5- and 4-substituted species.

M3 - Article

SP - 2864

EP - 2871

JO - Journal of the Chemical Society. Dalton Transactions

JF - Journal of the Chemical Society. Dalton Transactions

IS - 19

ER -

Redistribution of terpy ligands - approaches to new dynamic combinatorial libraries

Abstract

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