Rate constants and Arrhenius parameters for the reactions of OH radicals and Cl atoms with CF3CH2OCHF2, CF3CHClOCHF2 and CF3CH2OCClF2, using the discharge-flow/resonance fluorescence method

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@article{bfde6ca89a734b55a472300f909860a1,
title = "Rate constants and Arrhenius parameters for the reactions of OH radicals and Cl atoms with CF3CH2OCHF2, CF3CHClOCHF2 and CF3CH2OCClF2, using the discharge-flow/resonance fluorescence method",
abstract = "Rate constants were determined for the reactions of OH radicals and Cl atoms with the three partially halogenated methyl ethyl ethers, CF3CH2OCHF2, CF3CHClOCHF2 and CF3CH2OCClF2, using discharge-flow techniques to generate the OH radicals and the Cl atoms and resonance fluorescence to observe changes in their relative concentrations in the presence of added ether. For each combination of radical and ether, experiments were carried out at three temperatures between 292 and 410 K, yielding the following Arrhenius expressions for the rate constants within this range of temperature:The results are compared with those obtained previously for the same and related reactions of OH radicals and Cl atoms, and the atmospheric implications of the results are considered briefly.",
author = "Simon Beach and Kevin Hickson and Ian Smith and Richard Tuckett",
year = "2001",
month = jun,
day = "11",
doi = "10.1039/b103883b",
language = "English",
volume = "3",
pages = "3064--3069",
journal = "Physical Chemistry Chemical Physics",
issn = "1463-9076",
publisher = "Royal Society of Chemistry",
number = "15",

}

RIS

TY - JOUR

T1 - Rate constants and Arrhenius parameters for the reactions of OH radicals and Cl atoms with CF3CH2OCHF2, CF3CHClOCHF2 and CF3CH2OCClF2, using the discharge-flow/resonance fluorescence method

AU - Beach, Simon

AU - Hickson, Kevin

AU - Smith, Ian

AU - Tuckett, Richard

PY - 2001/6/11

Y1 - 2001/6/11

N2 - Rate constants were determined for the reactions of OH radicals and Cl atoms with the three partially halogenated methyl ethyl ethers, CF3CH2OCHF2, CF3CHClOCHF2 and CF3CH2OCClF2, using discharge-flow techniques to generate the OH radicals and the Cl atoms and resonance fluorescence to observe changes in their relative concentrations in the presence of added ether. For each combination of radical and ether, experiments were carried out at three temperatures between 292 and 410 K, yielding the following Arrhenius expressions for the rate constants within this range of temperature:The results are compared with those obtained previously for the same and related reactions of OH radicals and Cl atoms, and the atmospheric implications of the results are considered briefly.

AB - Rate constants were determined for the reactions of OH radicals and Cl atoms with the three partially halogenated methyl ethyl ethers, CF3CH2OCHF2, CF3CHClOCHF2 and CF3CH2OCClF2, using discharge-flow techniques to generate the OH radicals and the Cl atoms and resonance fluorescence to observe changes in their relative concentrations in the presence of added ether. For each combination of radical and ether, experiments were carried out at three temperatures between 292 and 410 K, yielding the following Arrhenius expressions for the rate constants within this range of temperature:The results are compared with those obtained previously for the same and related reactions of OH radicals and Cl atoms, and the atmospheric implications of the results are considered briefly.

U2 - 10.1039/b103883b

DO - 10.1039/b103883b

M3 - Article

VL - 3

SP - 3064

EP - 3069

JO - Physical Chemistry Chemical Physics

JF - Physical Chemistry Chemical Physics

SN - 1463-9076

IS - 15

ER -