RAFT dispersion polymerization: a method to tune the morphology of thymine-containing self-assemblies

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Colleges, School and Institutes


The synthesis and self-assembly of thymine-containing polymers were performed using RAFT dispersion polymerization. A combination of microscopy and scattering techniques was used to analyze the resultant complex morphologies. The primary observation from this study is that the obtained aggregates induced during the polymerization were well-defined despite the constituent copolymers possessing broad dispersities. Moreover, a variety of parameters, including the choice of polymerization solvent, the degree of polymerization of both blocks and the presence of an adenine-containing mediator, were observed to affect the resultant size and shape of the assembly.


Original languageEnglish
Pages (from-to)4984-4992
Number of pages9
JournalPolymer Chemistry
Issue number27
Early online date11 Jun 2015
Publication statusPublished - 21 Jul 2015