Abstract
The potential control over monomer sequence in the ring-opening metathesis polymerization of functional norbornenes is explored based on the difference in reactivity of endo and exo isomers. This kinetic approach allows the rapid consumption of the exo-norbornene and insertion onto the growing poly(norbornene) chain within a narrow region of the overall polymer chain, whilst maintaining a homogeneous backbone. We herein demonstrate that this can be achieved using a range of functional monomers easily derived from commercially available precursors while their polymerization is carried out in a controlled manner.
Original language | English |
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Pages (from-to) | 2246-2250 |
Number of pages | 5 |
Journal | Chemical Science |
Volume | 5 |
DOIs | |
Publication status | Published - 26 Mar 2014 |