Polymerisation resistant synthesis of methacrylamido phenylboronic acids

F D'Hooge; D Rogalle; MJ Thatcher; SP Perera; JMH van den Elsen; ATA Jenkins; TD James; John S. Fossey

doi:10.1016/j.polymer.2008.05.039

Polymerisation resistant synthesis of methacrylamido phenylboronic acids

F D'Hooge, D Rogalle, MJ Thatcher, SP Perera, JMH van den Elsen, ATA Jenkins, TD James, John S. Fossey

Chemistry

Research output: Contribution to journal › Article

22 Citations (Scopus)

Abstract

Acrylamido boronic acids are important building blocks for functional polymers but suffer from poor synthetic strategies and unwanted polymerisation. A two-step deprotection of pinacolato methacrylamido phenylene boronic esters to generate 2-, 3- and 4-methacrylamido phenylboronic acids in good yield and purity is reported. Boronic acid containing methacrylamido monomers are now available in good yields for incorporation into polymers. (C) 2008 Elsevier Ltd. All rights reserved.

Original language	English
Pages (from-to)	3362-3365
Number of pages	4
Journal	Polymer
Volume	49
Issue number	16
DOIs	https://doi.org/10.1016/j.polymer.2008.05.039
Publication status	Published - 28 Jul 2008

Keywords

acrylamide
boronic acid
deprotection

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10.1016/j.polymer.2008.05.039

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title = "Polymerisation resistant synthesis of methacrylamido phenylboronic acids",

abstract = "Acrylamido boronic acids are important building blocks for functional polymers but suffer from poor synthetic strategies and unwanted polymerisation. A two-step deprotection of pinacolato methacrylamido phenylene boronic esters to generate 2-, 3- and 4-methacrylamido phenylboronic acids in good yield and purity is reported. Boronic acid containing methacrylamido monomers are now available in good yields for incorporation into polymers. (C) 2008 Elsevier Ltd. All rights reserved.",

keywords = "acrylamide, boronic acid, deprotection",

author = "F D'Hooge and D Rogalle and MJ Thatcher and SP Perera and {van den Elsen}, JMH and ATA Jenkins and TD James and Fossey, {John S.}",

year = "2008",

month = jul,

day = "28",

doi = "10.1016/j.polymer.2008.05.039",

language = "English",

volume = "49",

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journal = "Polymer",

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number = "16",

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TY - JOUR

T1 - Polymerisation resistant synthesis of methacrylamido phenylboronic acids

AU - D'Hooge, F

AU - Rogalle, D

AU - Thatcher, MJ

AU - Perera, SP

AU - van den Elsen, JMH

AU - Jenkins, ATA

AU - James, TD

AU - Fossey, John S.

PY - 2008/7/28

Y1 - 2008/7/28

N2 - Acrylamido boronic acids are important building blocks for functional polymers but suffer from poor synthetic strategies and unwanted polymerisation. A two-step deprotection of pinacolato methacrylamido phenylene boronic esters to generate 2-, 3- and 4-methacrylamido phenylboronic acids in good yield and purity is reported. Boronic acid containing methacrylamido monomers are now available in good yields for incorporation into polymers. (C) 2008 Elsevier Ltd. All rights reserved.

AB - Acrylamido boronic acids are important building blocks for functional polymers but suffer from poor synthetic strategies and unwanted polymerisation. A two-step deprotection of pinacolato methacrylamido phenylene boronic esters to generate 2-, 3- and 4-methacrylamido phenylboronic acids in good yield and purity is reported. Boronic acid containing methacrylamido monomers are now available in good yields for incorporation into polymers. (C) 2008 Elsevier Ltd. All rights reserved.

KW - acrylamide

KW - boronic acid

KW - deprotection

U2 - 10.1016/j.polymer.2008.05.039

DO - 10.1016/j.polymer.2008.05.039

M3 - Article

VL - 49

SP - 3362

EP - 3365

JO - Polymer

JF - Polymer

IS - 16

ER -

Polymerisation resistant synthesis of methacrylamido phenylboronic acids

Abstract

Keywords

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