Photoinduced ring-opening polymerisation of L-lactide via a photocaged superbase

P. K. Kuroishi; A. P. Dove

doi:10.1039/C8CC01913D

Photoinduced ring-opening polymerisation of L-lactide via a photocaged superbase

P. K. Kuroishi, A. P. Dove

Chemistry

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

200 Downloads (Pure)

Abstract

The phototriggered ring-opening polymerisation of L-lactide is demonstrated for the first time using a photocaged tetramethylguanidine. The catalytic activity of the free guanidine was also investigated, showing it to be active for the polymerisation of δ-valerolactone and ε-caprolactone in the presence of a thiourea cocatalyst.

Original language	English
Pages (from-to)	6264-6267
Journal	Chemical Communications
Volume	54
Issue number	49
Early online date	17 Apr 2018
DOIs	https://doi.org/10.1039/C8CC01913D
Publication status	Published - 21 Jun 2018

Access to Document

10.1039/C8CC01913DLicence: Creative Commons: Attribution (CC BY)

Kuroishi_Dove_Photoinduced_ring-opening_ChemCommFinal published version, 2.51 MBLicence: Creative Commons: Attribution (CC BY)

Cite this

@article{4c6afcf954ce4a90bb572a48c150419b,

title = "Photoinduced ring-opening polymerisation of L-lactide via a photocaged superbase",

abstract = "The phototriggered ring-opening polymerisation of L-lactide is demonstrated for the first time using a photocaged tetramethylguanidine. The catalytic activity of the free guanidine was also investigated, showing it to be active for the polymerisation of δ-valerolactone and ε-caprolactone in the presence of a thiourea cocatalyst.",

author = "{K. Kuroishi}, P. and Dove, {A. P.}",

year = "2018",

month = jun,

day = "21",

doi = "10.1039/C8CC01913D",

language = "English",

volume = "54",

pages = "6264--6267",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "49",

}

TY - JOUR

T1 - Photoinduced ring-opening polymerisation of L-lactide via a photocaged superbase

AU - K. Kuroishi, P.

AU - Dove, A. P.

PY - 2018/6/21

Y1 - 2018/6/21

N2 - The phototriggered ring-opening polymerisation of L-lactide is demonstrated for the first time using a photocaged tetramethylguanidine. The catalytic activity of the free guanidine was also investigated, showing it to be active for the polymerisation of δ-valerolactone and ε-caprolactone in the presence of a thiourea cocatalyst.

AB - The phototriggered ring-opening polymerisation of L-lactide is demonstrated for the first time using a photocaged tetramethylguanidine. The catalytic activity of the free guanidine was also investigated, showing it to be active for the polymerisation of δ-valerolactone and ε-caprolactone in the presence of a thiourea cocatalyst.

U2 - 10.1039/C8CC01913D

DO - 10.1039/C8CC01913D

M3 - Article

SN - 1359-7345

VL - 54

SP - 6264

EP - 6267

JO - Chemical Communications

JF - Chemical Communications

IS - 49

ER -

Photoinduced ring-opening polymerisation of L-lactide via a photocaged superbase

Abstract

Access to Document

Fingerprint

Cite this