TY - JOUR
T1 - Photochemical or thermal chelate exchange in the ruthenium coordination sphere of complexes of the Ru(phen)2L family (L = diimine or dinitrile ligands)
AU - Baranoff, Etienne
AU - Collin, Jean Paul
AU - Furusho, Junko
AU - Furusho, Yoshio
AU - Laemmel, Anne Chantal
AU - Sauvage, Jean Pierre
AU - Baranoff, Etienne
PY - 2002/3/11
Y1 - 2002/3/11
N2 - Complexes of the type Ru(phen)2L2+, where L is a substituted bipyridine family member, have been prepared, and their photochemical substitution reactions have been investigated. In the presence of a bis-benzonitrile derivative, acting as a bidentate chelate, photoexpulsion of L is performed under the action of visible light, with quantitative formation of new complexes of the type Ru(phen)2L′2+ (L′ = bis-nitrile ligand). Several complexes have been characterized by X-ray crystallography. In particular, the bis-benzonitrile complexes could be crystallized, and the structure of these compounds, containing a 13-, 14-, or 15-membered metal incorporating ring, was obtained. By heating Ru(phen)2L′2+ with a bipy derivative in refluxing ethylene glycol, quantitative formation of the starting complex [Ru(phen)2L2+] was carried out. The present series of compounds presents properties that could be profitably used in the design and construction of multicomponent systems acting as photochemically driven molecular machines.
AB - Complexes of the type Ru(phen)2L2+, where L is a substituted bipyridine family member, have been prepared, and their photochemical substitution reactions have been investigated. In the presence of a bis-benzonitrile derivative, acting as a bidentate chelate, photoexpulsion of L is performed under the action of visible light, with quantitative formation of new complexes of the type Ru(phen)2L′2+ (L′ = bis-nitrile ligand). Several complexes have been characterized by X-ray crystallography. In particular, the bis-benzonitrile complexes could be crystallized, and the structure of these compounds, containing a 13-, 14-, or 15-membered metal incorporating ring, was obtained. By heating Ru(phen)2L′2+ with a bipy derivative in refluxing ethylene glycol, quantitative formation of the starting complex [Ru(phen)2L2+] was carried out. The present series of compounds presents properties that could be profitably used in the design and construction of multicomponent systems acting as photochemically driven molecular machines.
UR - http://www.scopus.com/inward/record.url?scp=0037061155&partnerID=8YFLogxK
U2 - 10.1021/ic011014o
DO - 10.1021/ic011014o
M3 - Article
C2 - 11874358
AN - SCOPUS:0037061155
SN - 0020-1669
VL - 41
SP - 1215
EP - 1222
JO - Inorganic Chemistry
JF - Inorganic Chemistry
IS - 5
ER -