Photochemical control of molecular motion associated with pyramidal inversion

Research output: Contribution to journalArticle

Authors

  • Alexander J Hough
  • Ivan Prokes
  • Jim Tucker
  • Michael Shipman
  • Tiffany R Walsh

Colleges, School and Institutes

External organisations

  • Department of Chemistry, University of Warwick, Gibbet Hill Road, Coventry, CV4 7AL, UK.

Abstract

Rates of pyramidal motion in an aziridine are controlled by reversible trans to cis photoisomerisation of an azobenzene unit attached to the ring nitrogen atom. The dynamics of the inversion process and activation parameters are derived by variable temperature NMR, and are supported by ab initio calculations.

Details

Original languageEnglish
Pages (from-to)6683-5
Number of pages3
JournalChemical Communications
Volume49
Issue number59
Publication statusPublished - 28 Jul 2013

Keywords

  • Aziridines, Molecular Structure, Motion, Photochemical Processes, Pyrimidines, Quantum Theory, Stereoisomerism