Palladium and Platinum 2,4-cis-amino Azetidine and Related Complexes

Research output: Contribution to journalArticle

Authors

  • Akina Yoshizawa
  • Antonio Feula
  • Andrew G Leach
  • Louise Male
  • John Fossey

Colleges, School and Institutes

Abstract

Seven N,N'-palladium(II) chloride complexes, one N,N'-palladium(II) acetate complex of 2,4-cis-azetidines where prepared and analyzed by single crystal XRD. Two platinum(II) chloride N,N'-complexes of 2,4-cis-azetidines where prepared and analyzed by single crystal XRD. Computational analysis and determination of the %Vbur was examined conducted. A CNN' metallocyclic complex was prepared by oxidative addition of palladium(0) to an ortho bromo 2,4-cis-disubstituted azetidine and its crystal structure displays a slightly pyramidalized metal-ligand orientation.

Details

Original languageEnglish
Article number211
JournalFrontiers in Chemistry
Volume6
Publication statusPublished - 21 Jun 2018