On the coordination chemistry of phosphinecarboxamide:  assessing ligand basicity

M. B. Geeson; A. R. Jupp; J. E. McGrady; J. M. Goicoechea

doi:10.1039/c4cc06094f

On the coordination chemistry of phosphinecarboxamide: assessing ligand basicity

M. B. Geeson, A. R. Jupp, J. E. McGrady, J. M. Goicoechea

Chemistry

Research output: Contribution to journal › Article › peer-review

29 Citations (Scopus)

Abstract

We describe the coordination chemistry of the primary phosphine PH2C(O)NH2 (phosphinecarboxamide) towards group 6 transition-metals. Experimental and theoretical studies reveal that this novel species has comparable electronic properties to PH3.

Original language	English
Pages (from-to)	12281-12284
Number of pages	4
Journal	Chemical Communications
Volume	50
DOIs	https://doi.org/10.1039/c4cc06094f
Publication status	Published - 27 Aug 2014

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title = "On the coordination chemistry of phosphinecarboxamide: assessing ligand basicity",

abstract = "We describe the coordination chemistry of the primary phosphine PH2C(O)NH2 (phosphinecarboxamide) towards group 6 transition-metals. Experimental and theoretical studies reveal that this novel species has comparable electronic properties to PH3.",

author = "Geeson, {M. B.} and Jupp, {A. R.} and McGrady, {J. E.} and Goicoechea, {J. M.}",

year = "2014",

month = aug,

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doi = "10.1039/c4cc06094f",

language = "English",

volume = "50",

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journal = "Chemical Communications ",

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publisher = "Royal Society of Chemistry",

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T1 - On the coordination chemistry of phosphinecarboxamide

T2 - assessing ligand basicity

AU - Geeson, M. B.

AU - Jupp, A. R.

AU - McGrady, J. E.

AU - Goicoechea, J. M.

PY - 2014/8/27

Y1 - 2014/8/27

N2 - We describe the coordination chemistry of the primary phosphine PH2C(O)NH2 (phosphinecarboxamide) towards group 6 transition-metals. Experimental and theoretical studies reveal that this novel species has comparable electronic properties to PH3.

AB - We describe the coordination chemistry of the primary phosphine PH2C(O)NH2 (phosphinecarboxamide) towards group 6 transition-metals. Experimental and theoretical studies reveal that this novel species has comparable electronic properties to PH3.

U2 - 10.1039/c4cc06094f

DO - 10.1039/c4cc06094f

M3 - Article

SN - 1359-7345

VL - 50

SP - 12281

EP - 12284

JO - Chemical Communications

JF - Chemical Communications

ER -

On the coordination chemistry of phosphinecarboxamide: assessing ligand basicity

Abstract

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