Nanocomposites containing neutral blue emitting cyclometalated iridium(III) emitters for oxygen sensing

Marta Marín-Suárez; Basile F E Curchod; Ivano Tavernelli; Ursula Rothlisberger; Rosario Scopelliti; Il Jung; Davide Di Censo; Michael Grätzel; Jorge Fernando Fernández-Sánchez; Alberto Fernández-Gutiérrez; Md Khaja Nazeeruddin; Etienne Baranoff

doi:10.1021/cm300575z

Nanocomposites containing neutral blue emitting cyclometalated iridium(III) emitters for oxygen sensing

Marta Marín-Suárez, Basile F E Curchod, Ivano Tavernelli, Ursula Rothlisberger, Rosario Scopelliti, Il Jung, Davide Di Censo, Michael Grätzel, Jorge Fernando Fernández-Sánchez^*, Alberto Fernández-Gutiérrez, Md Khaja Nazeeruddin, Etienne Baranoff

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

59 Citations (Scopus)

Abstract

The behavior toward oxygen sensing of nanocomposites made of the aluminum oxide-hydroxide nanostructured solid support (AP200/19) and neutral blue emitting cyclometalated iridium(III) complexes was studied. The results are compared with the same dyes immobilized in polystyrene films. Since the photoluminescence of the complexes is totally quenched for oxygen concentrations just over 10%, these systems using the blue region of the visible spectrum are promising for oxygen detection at low concentration. In particular, dyes supported into the AP200/19 provide the best sensitivity to oxygen concentration, with the possibility to detect oxygen below 1% O ₂ in gas (0.01 bar).

Original language	English
Pages (from-to)	2330-2338
Number of pages	9
Journal	Chemistry of Materials
Volume	24
Issue number	12
DOIs	https://doi.org/10.1021/cm300575z
Publication status	Published - 26 Jun 2012

Keywords

cyclometalated iridium(III) complexes
nanostructured films
oxygen sensing
phosphorescence

ASJC Scopus subject areas

Materials Chemistry
Chemical Engineering(all)
Chemistry(all)

Access to Document

10.1021/cm300575z

Cite this

Marín-Suárez, M., Curchod, B. F. E., Tavernelli, I., Rothlisberger, U., Scopelliti, R., Jung, I., Di Censo, D., Grätzel, M., Fernández-Sánchez, J. F., Fernández-Gutiérrez, A., Nazeeruddin, M. K., & Baranoff, E. (2012). Nanocomposites containing neutral blue emitting cyclometalated iridium(III) emitters for oxygen sensing. Chemistry of Materials, 24(12), 2330-2338. https://doi.org/10.1021/cm300575z

@article{96af189792d44c7e98dccfd393a6c36e,

title = "Nanocomposites containing neutral blue emitting cyclometalated iridium(III) emitters for oxygen sensing",

abstract = "The behavior toward oxygen sensing of nanocomposites made of the aluminum oxide-hydroxide nanostructured solid support (AP200/19) and neutral blue emitting cyclometalated iridium(III) complexes was studied. The results are compared with the same dyes immobilized in polystyrene films. Since the photoluminescence of the complexes is totally quenched for oxygen concentrations just over 10%, these systems using the blue region of the visible spectrum are promising for oxygen detection at low concentration. In particular, dyes supported into the AP200/19 provide the best sensitivity to oxygen concentration, with the possibility to detect oxygen below 1% O 2 in gas (0.01 bar).",

keywords = "cyclometalated iridium(III) complexes, nanostructured films, oxygen sensing, phosphorescence",

author = "Marta Mar{\'i}n-Su{\'a}rez and Curchod, {Basile F E} and Ivano Tavernelli and Ursula Rothlisberger and Rosario Scopelliti and Il Jung and {Di Censo}, Davide and Michael Gr{\"a}tzel and Fern{\'a}ndez-S{\'a}nchez, {Jorge Fernando} and Alberto Fern{\'a}ndez-Guti{\'e}rrez and Nazeeruddin, {Md Khaja} and Etienne Baranoff",

year = "2012",

month = jun,

day = "26",

doi = "10.1021/cm300575z",

language = "English",

volume = "24",

pages = "2330--2338",

journal = "Chemistry of Materials",

issn = "0897-4756",

publisher = "American Chemical Society",

number = "12",

}

Marín-Suárez, M, Curchod, BFE, Tavernelli, I, Rothlisberger, U, Scopelliti, R, Jung, I, Di Censo, D, Grätzel, M, Fernández-Sánchez, JF, Fernández-Gutiérrez, A, Nazeeruddin, MK & Baranoff, E 2012, 'Nanocomposites containing neutral blue emitting cyclometalated iridium(III) emitters for oxygen sensing', Chemistry of Materials, vol. 24, no. 12, pp. 2330-2338. https://doi.org/10.1021/cm300575z

TY - JOUR

T1 - Nanocomposites containing neutral blue emitting cyclometalated iridium(III) emitters for oxygen sensing

AU - Marín-Suárez, Marta

AU - Curchod, Basile F E

AU - Tavernelli, Ivano

AU - Rothlisberger, Ursula

AU - Scopelliti, Rosario

AU - Jung, Il

AU - Di Censo, Davide

AU - Grätzel, Michael

AU - Fernández-Sánchez, Jorge Fernando

AU - Fernández-Gutiérrez, Alberto

AU - Nazeeruddin, Md Khaja

AU - Baranoff, Etienne

PY - 2012/6/26

Y1 - 2012/6/26

N2 - The behavior toward oxygen sensing of nanocomposites made of the aluminum oxide-hydroxide nanostructured solid support (AP200/19) and neutral blue emitting cyclometalated iridium(III) complexes was studied. The results are compared with the same dyes immobilized in polystyrene films. Since the photoluminescence of the complexes is totally quenched for oxygen concentrations just over 10%, these systems using the blue region of the visible spectrum are promising for oxygen detection at low concentration. In particular, dyes supported into the AP200/19 provide the best sensitivity to oxygen concentration, with the possibility to detect oxygen below 1% O 2 in gas (0.01 bar).

AB - The behavior toward oxygen sensing of nanocomposites made of the aluminum oxide-hydroxide nanostructured solid support (AP200/19) and neutral blue emitting cyclometalated iridium(III) complexes was studied. The results are compared with the same dyes immobilized in polystyrene films. Since the photoluminescence of the complexes is totally quenched for oxygen concentrations just over 10%, these systems using the blue region of the visible spectrum are promising for oxygen detection at low concentration. In particular, dyes supported into the AP200/19 provide the best sensitivity to oxygen concentration, with the possibility to detect oxygen below 1% O 2 in gas (0.01 bar).

KW - cyclometalated iridium(III) complexes

KW - nanostructured films

KW - oxygen sensing

KW - phosphorescence

UR - http://www.scopus.com/inward/record.url?scp=84862900142&partnerID=8YFLogxK

U2 - 10.1021/cm300575z

DO - 10.1021/cm300575z

M3 - Article

AN - SCOPUS:84862900142

SN - 0897-4756

VL - 24

SP - 2330

EP - 2338

JO - Chemistry of Materials

JF - Chemistry of Materials

IS - 12

ER -

Nanocomposites containing neutral blue emitting cyclometalated iridium(III) emitters for oxygen sensing

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Fingerprint

Cite this