Multimodal switching of a redox-active macrocycle

Research output: Contribution to journalArticlepeer-review

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Multimodal switching of a redox-active macrocycle. / Payne, Daniel T.; Webre, Whitney A.; Matsushita, Yoshitaka; Zhu, Nianyong; Futera, Zdenĕk; Labuta, Jan; Jevasuwan, Wipakorn; Fukata, Naoki; Fossey, John S.; D’Souza, Francis; Ariga, Katsuhiko; Schmitt, Wolfgang; Hill, Jonathan P.

In: Nature Communications, Vol. 10, 1007 , 01.03.2019.

Research output: Contribution to journalArticlepeer-review

Harvard

Payne, DT, Webre, WA, Matsushita, Y, Zhu, N, Futera, Z, Labuta, J, Jevasuwan, W, Fukata, N, Fossey, JS, D’Souza, F, Ariga, K, Schmitt, W & Hill, JP 2019, 'Multimodal switching of a redox-active macrocycle', Nature Communications, vol. 10, 1007 . https://doi.org/10.1038/s41467-019-08978-5

APA

Payne, D. T., Webre, W. A., Matsushita, Y., Zhu, N., Futera, Z., Labuta, J., Jevasuwan, W., Fukata, N., Fossey, J. S., D’Souza, F., Ariga, K., Schmitt, W., & Hill, J. P. (2019). Multimodal switching of a redox-active macrocycle. Nature Communications, 10, [1007 ]. https://doi.org/10.1038/s41467-019-08978-5

Vancouver

Payne DT, Webre WA, Matsushita Y, Zhu N, Futera Z, Labuta J et al. Multimodal switching of a redox-active macrocycle. Nature Communications. 2019 Mar 1;10. 1007 . https://doi.org/10.1038/s41467-019-08978-5

Author

Payne, Daniel T. ; Webre, Whitney A. ; Matsushita, Yoshitaka ; Zhu, Nianyong ; Futera, Zdenĕk ; Labuta, Jan ; Jevasuwan, Wipakorn ; Fukata, Naoki ; Fossey, John S. ; D’Souza, Francis ; Ariga, Katsuhiko ; Schmitt, Wolfgang ; Hill, Jonathan P. / Multimodal switching of a redox-active macrocycle. In: Nature Communications. 2019 ; Vol. 10.

Bibtex

@article{7ae845db26ef42a79c6c3ac758e1c876,
title = "Multimodal switching of a redox-active macrocycle",
abstract = "Molecules that can exist in multiple states with the possibility of toggling between those states based on different stimuli have potential for use in molecular switching or sensing applications. Multimodal chemical or photochemical oxidative switching of an antioxidant-substituted resorcinarene macrocycle is reported. Intramolecular charge-transfer states, involving hemiquinhydrones are probed and these interactions are used to construct an oxidation-state-coupled molecular switching manifold that reports its switch-state conformation via striking variation in its electronic absorption spectra. The coupling of two different oxidation states with two different charge-transfer states within one macrocyclic scaffold delivers up to five different optical outputs. This molecular switching manifold exploits intramolecular coupling of multiple redox active substituents within a single molecule.",
author = "Payne, {Daniel T.} and Webre, {Whitney A.} and Yoshitaka Matsushita and Nianyong Zhu and Zdenĕk Futera and Jan Labuta and Wipakorn Jevasuwan and Naoki Fukata and Fossey, {John S.} and Francis D{\textquoteright}Souza and Katsuhiko Ariga and Wolfgang Schmitt and Hill, {Jonathan P.}",
year = "2019",
month = mar,
day = "1",
doi = "10.1038/s41467-019-08978-5",
language = "English",
volume = "10",
journal = "Nature Communications",
issn = "2041-1723",
publisher = "Springer",

}

RIS

TY - JOUR

T1 - Multimodal switching of a redox-active macrocycle

AU - Payne, Daniel T.

AU - Webre, Whitney A.

AU - Matsushita, Yoshitaka

AU - Zhu, Nianyong

AU - Futera, Zdenĕk

AU - Labuta, Jan

AU - Jevasuwan, Wipakorn

AU - Fukata, Naoki

AU - Fossey, John S.

AU - D’Souza, Francis

AU - Ariga, Katsuhiko

AU - Schmitt, Wolfgang

AU - Hill, Jonathan P.

PY - 2019/3/1

Y1 - 2019/3/1

N2 - Molecules that can exist in multiple states with the possibility of toggling between those states based on different stimuli have potential for use in molecular switching or sensing applications. Multimodal chemical or photochemical oxidative switching of an antioxidant-substituted resorcinarene macrocycle is reported. Intramolecular charge-transfer states, involving hemiquinhydrones are probed and these interactions are used to construct an oxidation-state-coupled molecular switching manifold that reports its switch-state conformation via striking variation in its electronic absorption spectra. The coupling of two different oxidation states with two different charge-transfer states within one macrocyclic scaffold delivers up to five different optical outputs. This molecular switching manifold exploits intramolecular coupling of multiple redox active substituents within a single molecule.

AB - Molecules that can exist in multiple states with the possibility of toggling between those states based on different stimuli have potential for use in molecular switching or sensing applications. Multimodal chemical or photochemical oxidative switching of an antioxidant-substituted resorcinarene macrocycle is reported. Intramolecular charge-transfer states, involving hemiquinhydrones are probed and these interactions are used to construct an oxidation-state-coupled molecular switching manifold that reports its switch-state conformation via striking variation in its electronic absorption spectra. The coupling of two different oxidation states with two different charge-transfer states within one macrocyclic scaffold delivers up to five different optical outputs. This molecular switching manifold exploits intramolecular coupling of multiple redox active substituents within a single molecule.

UR - https://doi.org/10.1038/s41467-019-08978-5

U2 - 10.1038/s41467-019-08978-5

DO - 10.1038/s41467-019-08978-5

M3 - Article

C2 - 30824697

VL - 10

JO - Nature Communications

JF - Nature Communications

SN - 2041-1723

M1 - 1007

ER -