Measurement of the state‐specific differential cross section for the H+D2→HD(v′=4, J′=3)+D reaction at a collision energy of 2.2 eV

Neil E. Shafer‐Ray; Frédéric Merkt; Daniel J. Hughes; Michael Springer; Richard P. Tuckett; Richard N. Zare

doi:10.1063/1.470604

Measurement of the state‐specific differential cross section for the H+D2→HD(v′=4, J′=3)+D reaction at a collision energy of 2.2 eV

Neil E. Shafer‐Ray, Frédéric Merkt, Daniel J. Hughes, Michael Springer, Richard P. Tuckett, Richard N. Zare

Chemistry

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Abstract

HI and D2 are coexpanded into a vacuum chamber. The photolysis of HI at 212.8 nm initiates the H+D2 reaction. The HD(v=4,J′=3) velocity distribution is determined by analyzing the time‐of‐flight profile of HD+ ions produced by delayed pulsed field ionization of long‐lived Rydberg states. The angular distribution is deduced using the law of cosines (photoloc technique).

Original language	English
Pages (from-to)	5157-5160
Journal	Journal of Chemical Physics
Volume	103
Issue number	12
DOIs	https://doi.org/10.1063/1.470604
Publication status	Published - 22 Sept 1995

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Xu_et_al_Measurement_of_the_state_Journal_of_Chemical_Physics_1995
Measurement of the state‐specific differential cross section for the H+D2→HD(v′=4, J′=3)+D reaction at a collision energy of 2.2 eV. Hao Xu, Neil E. Shafer‐Ray, Frédéric Merkt, Daniel J. Hughes, Michael Springer, Richard P. Tuckett, and Richard N. Zare. The Journal of Chemical Physics 1995 103:12, 5157-5160
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http://aip.scitation.org/doi/10.1063/1.470604Licence: None: All rights reserved

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title = "Measurement of the state‐specific differential cross section for the H+D2→HD(v′=4, J′=3)+D reaction at a collision energy of 2.2 eV",

abstract = "HI and D2 are coexpanded into a vacuum chamber. The photolysis of HI at 212.8 nm initiates the H+D2 reaction. The HD(v=4,J′=3) velocity distribution is determined by analyzing the time‐of‐flight profile of HD+ ions produced by delayed pulsed field ionization of long‐lived Rydberg states. The angular distribution is deduced using the law of cosines (photoloc technique).",

author = "Shafer‐Ray, {Neil E.} and Fr{\'e}d{\'e}ric Merkt and Hughes, {Daniel J.} and Michael Springer and Tuckett, {Richard P.} and Zare, {Richard N.}",

year = "1995",

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T1 - Measurement of the state‐specific differential cross section for the H+D2→HD(v′=4, J′=3)+D reaction at a collision energy of 2.2 eV

AU - Shafer‐Ray, Neil E.

AU - Merkt, Frédéric

AU - Hughes, Daniel J.

AU - Springer, Michael

AU - Tuckett, Richard P.

AU - Zare, Richard N.

PY - 1995/9/22

Y1 - 1995/9/22

N2 - HI and D2 are coexpanded into a vacuum chamber. The photolysis of HI at 212.8 nm initiates the H+D2 reaction. The HD(v=4,J′=3) velocity distribution is determined by analyzing the time‐of‐flight profile of HD+ ions produced by delayed pulsed field ionization of long‐lived Rydberg states. The angular distribution is deduced using the law of cosines (photoloc technique).

AB - HI and D2 are coexpanded into a vacuum chamber. The photolysis of HI at 212.8 nm initiates the H+D2 reaction. The HD(v=4,J′=3) velocity distribution is determined by analyzing the time‐of‐flight profile of HD+ ions produced by delayed pulsed field ionization of long‐lived Rydberg states. The angular distribution is deduced using the law of cosines (photoloc technique).

U2 - 10.1063/1.470604

DO - 10.1063/1.470604

M3 - Article

SN - 0021-9606

VL - 103

SP - 5157

EP - 5160

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 12

ER -

Measurement of the state‐specific differential cross section for the H+D2→HD(v′=4, J′=3)+D reaction at a collision energy of 2.2 eV

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