TY - JOUR
T1 - Marcus theory for outer-sphere heterogeneous electron transfer
T2 - Predicting electron-transfer rates for quinones
AU - Rees, N.V.
AU - Clegg, A.D.
AU - Klymenko, O.V.
AU - Coles, B.A.
AU - Compton, R.G.
N1 - Copyright 2009 Elsevier B.V., All rights reserved.
PY - 2004/8/26
Y1 - 2004/8/26
N2 - Steady-state voltammetry is used to measure the heterogeneous electron-transfer rates for the reduction of quinones to determine the dependence of k on molecular size, according to Marcus theory. This dependence is then used to predict the electron-transfer rate constants of related quinones, and the predictions are compared to experimental measurements.
AB - Steady-state voltammetry is used to measure the heterogeneous electron-transfer rates for the reduction of quinones to determine the dependence of k on molecular size, according to Marcus theory. This dependence is then used to predict the electron-transfer rate constants of related quinones, and the predictions are compared to experimental measurements.
UR - http://www.scopus.com/inward/record.url?partnerID=yv4JPVwI&eid=2-s2.0-4444342316&md5=e943e5b88be6e270da932627a9fd3834
U2 - 10.1021/jp0403821
DO - 10.1021/jp0403821
M3 - Article
AN - SCOPUS:4444342316
SN - 1520-6106
VL - 108
SP - 13047
EP - 13051
JO - The Journal of Physical Chemistry Part B: Condensed Matter, Materials, Surfaces, Interfaces & Biophysical
JF - The Journal of Physical Chemistry Part B: Condensed Matter, Materials, Surfaces, Interfaces & Biophysical
IS - 34
ER -