Projects per year
Abstract
The tip of a scanning tunnelling microscope is an atomic-scale source of electrons and holes. As the injected charge spreads out, it can induce adsorbed molecules to react. By comparing large-scale 'before' and 'after' images of an adsorbate covered surface, the spatial extent of the nonlocal manipulation is revealed. Here, we measure the nonlocal manipulation of toluene molecules on the Si(111)-7 × 7 surface at room temperature. Both the range and probability of nonlocal manipulation have a voltage dependence. A region within 5-15 nm of the injection site shows a marked reduction in manipulation. We propose that this region marks the extent of the initial coherent (that is, ballistic) time-dependent evolution of the injected charge carrier. Using scanning tunnelling spectroscopy, we develop a model of this time-dependent expansion of the initially localized hole wavepacket within a particular surface state and deduce a quantum coherence (ballistic) lifetime of ∼10 fs.
Original language | English |
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Article number | 12839 |
Journal | Nature Communications |
Volume | 7 |
DOIs | |
Publication status | Published - 28 Sept 2016 |
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Dive into the research topics of 'Initiating and imaging the coherent surface dynamics of charge carriers in real space'. Together they form a unique fingerprint.Projects
- 2 Finished
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Atomic Manipulation at Room Temperature
Palmer, R.
Engineering & Physical Science Research Council
1/12/06 → 30/11/09
Project: Research Councils