In situ TEM observation of a microcrucible mechanism of nanowire growth
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In situ TEM observation of a microcrucible mechanism of nanowire growth. / Boston, Rebecca; Schnepp, Zoe; Nemoto, Yoshihiro; Sakka, Yoshio; Hall, Simon.
In: Science, Vol. 344, No. 6184, 09.05.2014, p. 623-626.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - In situ TEM observation of a microcrucible mechanism of nanowire growth
AU - Boston, Rebecca
AU - Schnepp, Zoe
AU - Nemoto, Yoshihiro
AU - Sakka, Yoshio
AU - Hall, Simon
PY - 2014/5/9
Y1 - 2014/5/9
N2 - The growth of metal oxide nanowires can proceed via a number of mechanisms such as screw dislocation, vapor-liquid-solid process, or seeded growth. Transmission electron microscopy (TEM) can resolve nanowires but invariably lacks the facility for direct observation of how nanowires form. We used a transmission electron microscope equipped with an in situ heating stage to follow the growth of quaternary metal oxide nanowires. Video-rate imaging revealed barium carbonate nanoparticles diffusing through a porous matrix containing copper and yttrium oxides to subsequently act as catalytic sites for the outgrowth of YBaCuO nanowires on reaching the surface. The results suggest that sites on the rough surface of the porous matrix act as microcrucibles and thus provide insights into the mechanisms that drive metal oxide nanowire growth at high temperatures.
AB - The growth of metal oxide nanowires can proceed via a number of mechanisms such as screw dislocation, vapor-liquid-solid process, or seeded growth. Transmission electron microscopy (TEM) can resolve nanowires but invariably lacks the facility for direct observation of how nanowires form. We used a transmission electron microscope equipped with an in situ heating stage to follow the growth of quaternary metal oxide nanowires. Video-rate imaging revealed barium carbonate nanoparticles diffusing through a porous matrix containing copper and yttrium oxides to subsequently act as catalytic sites for the outgrowth of YBaCuO nanowires on reaching the surface. The results suggest that sites on the rough surface of the porous matrix act as microcrucibles and thus provide insights into the mechanisms that drive metal oxide nanowire growth at high temperatures.
UR - http://www.scopus.com/inward/record.url?eid=2-s2.0-84900332433&partnerID=8YFLogxK
U2 - 10.1126/science.1251594
DO - 10.1126/science.1251594
M3 - Article
C2 - 24812400
AN - SCOPUS:84900332433
VL - 344
SP - 623
EP - 626
JO - Science
JF - Science
SN - 0036-8075
IS - 6184
ER -