High-pressure and -temperature ion exchange of aluminosilicate and gallosilicate natrolite.

GL Hill; E Bailey; MC Stennett; NC Hyatt; EM Maddrell; PF McMillan; Joseph Hriljac

doi:10.1021/ja205680c

High-pressure and -temperature ion exchange of aluminosilicate and gallosilicate natrolite.

GL Hill, E Bailey, MC Stennett, NC Hyatt, EM Maddrell, PF McMillan, Joseph Hriljac

Chemistry

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19 Citations (Scopus)

Abstract

The simultaneous application of high pressure and high temperature has been used to achieve direct ion exchange of large cesium cations for the small sodium cations found in the zeolite natrolite by putting it into a superhydrated state with increased pore size. The larger cations remain trapped upon pressure release, and thus, this method is a means of producing new cationic forms of zeolites.

Original language	English
Pages (from-to)	13883-5
Number of pages	3
Journal	Journal of the American Chemical Society
Volume	133
Issue number	35
DOIs	https://doi.org/10.1021/ja205680c
Publication status	Published - 7 Sept 2011

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title = "High-pressure and -temperature ion exchange of aluminosilicate and gallosilicate natrolite.",

abstract = "The simultaneous application of high pressure and high temperature has been used to achieve direct ion exchange of large cesium cations for the small sodium cations found in the zeolite natrolite by putting it into a superhydrated state with increased pore size. The larger cations remain trapped upon pressure release, and thus, this method is a means of producing new cationic forms of zeolites.",

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AU - Hill, GL

AU - Bailey, E

AU - Stennett, MC

AU - Hyatt, NC

AU - Maddrell, EM

AU - McMillan, PF

AU - Hriljac, Joseph

PY - 2011/9/7

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N2 - The simultaneous application of high pressure and high temperature has been used to achieve direct ion exchange of large cesium cations for the small sodium cations found in the zeolite natrolite by putting it into a superhydrated state with increased pore size. The larger cations remain trapped upon pressure release, and thus, this method is a means of producing new cationic forms of zeolites.

AB - The simultaneous application of high pressure and high temperature has been used to achieve direct ion exchange of large cesium cations for the small sodium cations found in the zeolite natrolite by putting it into a superhydrated state with increased pore size. The larger cations remain trapped upon pressure release, and thus, this method is a means of producing new cationic forms of zeolites.

U2 - 10.1021/ja205680c

DO - 10.1021/ja205680c

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EP - 13885

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 35

ER -

High-pressure and -temperature ion exchange of aluminosilicate and gallosilicate natrolite.

Abstract

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