TY - CHAP
T1 - Heterogeneous catalysis by frustrated Lewis pairs
AU - Jupp, Andrew
PY - 2020/11
Y1 - 2020/11
N2 - Frustrated Lewis pairs (FLPs), featuring reactive Lewis acid and Lewis base sites that can cooperatively activate small molecules, have been exploited in a wide range of homogeneous catalytic reactions since their inception in 2006. However, it is only recently that the tenets of FLP chemistry have been used to develop heterogeneous catalysts, which are advantageous due to their ease of separation from reaction mixtures and the recyclability of the catalyst. This chapter outlines the many different approaches that research groups around the world have taken to synthesise and utilise semi-immobilised or fully immobilised (solid-state) FLP catalysts. This includes supporting the Lewis acid and/or base components on or within a whole host of different materials, including silica, zeolites, metal-organic frameworks (MOFs), polyoxometalate clusters, metal oxides, graphene and hexagonal boron nitride.
AB - Frustrated Lewis pairs (FLPs), featuring reactive Lewis acid and Lewis base sites that can cooperatively activate small molecules, have been exploited in a wide range of homogeneous catalytic reactions since their inception in 2006. However, it is only recently that the tenets of FLP chemistry have been used to develop heterogeneous catalysts, which are advantageous due to their ease of separation from reaction mixtures and the recyclability of the catalyst. This chapter outlines the many different approaches that research groups around the world have taken to synthesise and utilise semi-immobilised or fully immobilised (solid-state) FLP catalysts. This includes supporting the Lewis acid and/or base components on or within a whole host of different materials, including silica, zeolites, metal-organic frameworks (MOFs), polyoxometalate clusters, metal oxides, graphene and hexagonal boron nitride.
KW - Heterogeneous catalysis
KW - Frustrated lewis pairs
KW - Solid-state
KW - MOFs
KW - Surfaces
UR - https://www.springer.com/gp/book/9783030588878
U2 - 10.1007/978-3-030-58888-5_7
DO - 10.1007/978-3-030-58888-5_7
M3 - Chapter
SN - 9783030588878
SN - 9783030588908
T3 - Molecular Catalysis (MOLCAT)
SP - 237
EP - 281
BT - Frustrated Lewis Pairs
A2 - null, J. Chris Slootweg
A2 - Jupp, Andrew R.
PB - Springer, Cham
ER -