Heterochiral triangulo nickel complex as evidence of a large positive nonlinear effect in catalysis

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Authors

Colleges, School and Institutes

External organisations

  • Ochanomizu University
  • University of Bath

Abstract

A novel triangulo complex was generated by heating, in vacuo, a racemic C-2-symmetric octahedral nickel(II) diamine complex. The trinuclear species was identified by single-crystai X-ray diffraction, which revealed a 2:1 ligand stereochemistry relationship in each unit. This solid-state structure evidences the hypothesis that a 1:2 stereochemical relationship lies at the heart of the strong positive nonlinear effect observed in enecarbamate aldol-like reactions catalyzed by nickel(II) diamine complexes.

Details

Original languageEnglish
Pages (from-to)781-783
Number of pages3
JournalInorganic Chemistry
Volume47
Issue number3
Publication statusPublished - 4 Feb 2008