Halogen-bonded cocrystallization with phosphorus, arsenic and antimony acceptors

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Halogen-bonded cocrystallization with phosphorus, arsenic and antimony acceptors. / Lisac, Katarina; Topić, Filip; Arhangelskis, Mihails; Cepić, Sara; Julien, Patrick A.; Nickels, Christopher W.; Morris, Andrew J.; Friščić, Tomislav; Cinčić, Dominik.

In: Nature Communications, Vol. 10, No. 1, 61, 04.01.2019.

Research output: Contribution to journalArticlepeer-review

Harvard

Lisac, K, Topić, F, Arhangelskis, M, Cepić, S, Julien, PA, Nickels, CW, Morris, AJ, Friščić, T & Cinčić, D 2019, 'Halogen-bonded cocrystallization with phosphorus, arsenic and antimony acceptors', Nature Communications, vol. 10, no. 1, 61. https://doi.org/10.1038/s41467-018-07957-6

APA

Lisac, K., Topić, F., Arhangelskis, M., Cepić, S., Julien, P. A., Nickels, C. W., Morris, A. J., Friščić, T., & Cinčić, D. (2019). Halogen-bonded cocrystallization with phosphorus, arsenic and antimony acceptors. Nature Communications, 10(1), [61]. https://doi.org/10.1038/s41467-018-07957-6

Vancouver

Lisac K, Topić F, Arhangelskis M, Cepić S, Julien PA, Nickels CW et al. Halogen-bonded cocrystallization with phosphorus, arsenic and antimony acceptors. Nature Communications. 2019 Jan 4;10(1). 61. https://doi.org/10.1038/s41467-018-07957-6

Author

Lisac, Katarina ; Topić, Filip ; Arhangelskis, Mihails ; Cepić, Sara ; Julien, Patrick A. ; Nickels, Christopher W. ; Morris, Andrew J. ; Friščić, Tomislav ; Cinčić, Dominik. / Halogen-bonded cocrystallization with phosphorus, arsenic and antimony acceptors. In: Nature Communications. 2019 ; Vol. 10, No. 1.

Bibtex

@article{d5c1f5c97bed4672ac3a5b846c3bd441,
title = "Halogen-bonded cocrystallization with phosphorus, arsenic and antimony acceptors",
abstract = "The formation of non-covalent directional interactions, such as hydrogen or halogen bonds, is a central concept of materials design, which hinges on using small compact atoms of the 2nd period, notably nitrogen and oxygen, as acceptors. Heavier atoms are much less prominent in that context, and mostly limited to sulfur. Here, we report the experimental observation and theoretical study of halogen bonds to phosphorus, arsenic and antimony in the solid state. Combining 1,3,5-trifluoro-2,4,6-triiodobenzene with triphenylphosphine, -arsine, and -stibine provides cocrystals based on I···P, I···As and I···Sb halogen bonds. The demonstration that increasingly metallic pnictogens form halogen bonds sufficiently strong to enable cocrystal formation is an advance in supramolecular chemistry which opens up opportunities in materials science, as shown by colossal thermal expansion of the cocrystal involving I···Sb halogen bonds.",
author = "Katarina Lisac and Filip Topi{\'c} and Mihails Arhangelskis and Sara Cepi{\'c} and Julien, {Patrick A.} and Nickels, {Christopher W.} and Morris, {Andrew J.} and Tomislav Fri{\v s}{\v c}i{\'c} and Dominik Cin{\v c}i{\'c}",
year = "2019",
month = jan,
day = "4",
doi = "10.1038/s41467-018-07957-6",
language = "English",
volume = "10",
journal = "Nature Communications",
issn = "2041-1723",
publisher = "Springer",
number = "1",

}

RIS

TY - JOUR

T1 - Halogen-bonded cocrystallization with phosphorus, arsenic and antimony acceptors

AU - Lisac, Katarina

AU - Topić, Filip

AU - Arhangelskis, Mihails

AU - Cepić, Sara

AU - Julien, Patrick A.

AU - Nickels, Christopher W.

AU - Morris, Andrew J.

AU - Friščić, Tomislav

AU - Cinčić, Dominik

PY - 2019/1/4

Y1 - 2019/1/4

N2 - The formation of non-covalent directional interactions, such as hydrogen or halogen bonds, is a central concept of materials design, which hinges on using small compact atoms of the 2nd period, notably nitrogen and oxygen, as acceptors. Heavier atoms are much less prominent in that context, and mostly limited to sulfur. Here, we report the experimental observation and theoretical study of halogen bonds to phosphorus, arsenic and antimony in the solid state. Combining 1,3,5-trifluoro-2,4,6-triiodobenzene with triphenylphosphine, -arsine, and -stibine provides cocrystals based on I···P, I···As and I···Sb halogen bonds. The demonstration that increasingly metallic pnictogens form halogen bonds sufficiently strong to enable cocrystal formation is an advance in supramolecular chemistry which opens up opportunities in materials science, as shown by colossal thermal expansion of the cocrystal involving I···Sb halogen bonds.

AB - The formation of non-covalent directional interactions, such as hydrogen or halogen bonds, is a central concept of materials design, which hinges on using small compact atoms of the 2nd period, notably nitrogen and oxygen, as acceptors. Heavier atoms are much less prominent in that context, and mostly limited to sulfur. Here, we report the experimental observation and theoretical study of halogen bonds to phosphorus, arsenic and antimony in the solid state. Combining 1,3,5-trifluoro-2,4,6-triiodobenzene with triphenylphosphine, -arsine, and -stibine provides cocrystals based on I···P, I···As and I···Sb halogen bonds. The demonstration that increasingly metallic pnictogens form halogen bonds sufficiently strong to enable cocrystal formation is an advance in supramolecular chemistry which opens up opportunities in materials science, as shown by colossal thermal expansion of the cocrystal involving I···Sb halogen bonds.

UR - http://www.scopus.com/inward/record.url?scp=85059494617&partnerID=8YFLogxK

U2 - 10.1038/s41467-018-07957-6

DO - 10.1038/s41467-018-07957-6

M3 - Article

VL - 10

JO - Nature Communications

JF - Nature Communications

SN - 2041-1723

IS - 1

M1 - 61

ER -