General Discussion: Electronic Emission Spectroscopy of CFFormula and SiFFormula: Appendix. The Sign of the Spin-Orbit Coupling Constant in (tFormula States of AXFormula Ions

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@article{7adf052836c04e6cbf3092aad0ff6f82,
title = "General Discussion:: Electronic Emission Spectroscopy of CFFormula and SiFFormula: Appendix. The Sign of the Spin-Orbit Coupling Constant in (tFormula States of AXFormula Ions",
abstract = "The spin-orbit splitting in orbitally degenerate systems with one open shell usually conforms to Hund{\textquoteright}s third rule: that is, the splitting is regular for a less than half-filled shell, and inverted for a more than half-filled shell. The C2T2 states of CF+4 and SiF+4 reported by Mason & Tuckett violate this expectation. We show below how this may occur in AX+4 ions where the dominant atomic spin-orbit coupling arises from motion around the X atoms.",
author = "Mason, {S. M.} and Tuckett, {R. P.} and Dixon, {R. N.}",
year = "1988",
month = jan,
day = "26",
doi = "10.1098/rsta.1988.0019",
language = "English",
volume = "324",
pages = "293--294",
journal = "Royal Society of London. Philosophical Transactions A. Mathematical, Physical and Engineering Sciences ",
issn = "1364-503X",
publisher = "The Royal Society",
number = "1578",

}

RIS

TY - JOUR

T1 - General Discussion:

T2 - Electronic Emission Spectroscopy of CFFormula and SiFFormula: Appendix. The Sign of the Spin-Orbit Coupling Constant in (tFormula States of AXFormula Ions

AU - Mason, S. M.

AU - Tuckett, R. P.

AU - Dixon, R. N.

PY - 1988/1/26

Y1 - 1988/1/26

N2 - The spin-orbit splitting in orbitally degenerate systems with one open shell usually conforms to Hund’s third rule: that is, the splitting is regular for a less than half-filled shell, and inverted for a more than half-filled shell. The C2T2 states of CF+4 and SiF+4 reported by Mason & Tuckett violate this expectation. We show below how this may occur in AX+4 ions where the dominant atomic spin-orbit coupling arises from motion around the X atoms.

AB - The spin-orbit splitting in orbitally degenerate systems with one open shell usually conforms to Hund’s third rule: that is, the splitting is regular for a less than half-filled shell, and inverted for a more than half-filled shell. The C2T2 states of CF+4 and SiF+4 reported by Mason & Tuckett violate this expectation. We show below how this may occur in AX+4 ions where the dominant atomic spin-orbit coupling arises from motion around the X atoms.

U2 - 10.1098/rsta.1988.0019

DO - 10.1098/rsta.1988.0019

M3 - Article

VL - 324

SP - 293

EP - 294

JO - Royal Society of London. Philosophical Transactions A. Mathematical, Physical and Engineering Sciences

JF - Royal Society of London. Philosophical Transactions A. Mathematical, Physical and Engineering Sciences

SN - 1364-503X

IS - 1578

ER -