Functional Degradable Polymers by Xanthate-Mediated Polymerization

Research output: Contribution to journalArticlepeer-review

Standard

Functional Degradable Polymers by Xanthate-Mediated Polymerization. / Hedir, Guillaume G.; Bell, Craig A.; Ieong, Nga Sze; Chapman, Emma; Collins, Ian R.; O'Reilly, Rachel K.; Dove, Andrew P.

In: Macromolecules, Vol. 47, No. 9, 23.04.2014, p. 2847-2852.

Research output: Contribution to journalArticlepeer-review

Harvard

Hedir, GG, Bell, CA, Ieong, NS, Chapman, E, Collins, IR, O'Reilly, RK & Dove, AP 2014, 'Functional Degradable Polymers by Xanthate-Mediated Polymerization', Macromolecules, vol. 47, no. 9, pp. 2847-2852. https://doi.org/10.1021/ma500428e

APA

Hedir, G. G., Bell, C. A., Ieong, N. S., Chapman, E., Collins, I. R., O'Reilly, R. K., & Dove, A. P. (2014). Functional Degradable Polymers by Xanthate-Mediated Polymerization. Macromolecules, 47(9), 2847-2852. https://doi.org/10.1021/ma500428e

Vancouver

Hedir GG, Bell CA, Ieong NS, Chapman E, Collins IR, O'Reilly RK et al. Functional Degradable Polymers by Xanthate-Mediated Polymerization. Macromolecules. 2014 Apr 23;47(9):2847-2852. https://doi.org/10.1021/ma500428e

Author

Hedir, Guillaume G. ; Bell, Craig A. ; Ieong, Nga Sze ; Chapman, Emma ; Collins, Ian R. ; O'Reilly, Rachel K. ; Dove, Andrew P. / Functional Degradable Polymers by Xanthate-Mediated Polymerization. In: Macromolecules. 2014 ; Vol. 47, No. 9. pp. 2847-2852.

Bibtex

@article{643da254f7e24f65996286b620750591,
title = "Functional Degradable Polymers by Xanthate-Mediated Polymerization",
abstract = "Herein we report the first example of the controlled synthesis of linear and hyperbranched copolymers of 2-methylene-1,3-dioxepane (MDO) with functional vinyl monomers to deliver a range of functional, degradable polymers by reversible deactivation radical polymerization. The copolymerization was able to be tuned to vary the incorporation of degradable segments to create degradable materials with predictable molar mass, low dispersity values while also featuring side-chain functionality. The formation of nanoparticles by the addition of divinyladipate to form degradable hyperbranched copolymers was proven by DLS and TEM analyses.",
author = "Hedir, {Guillaume G.} and Bell, {Craig A.} and Ieong, {Nga Sze} and Emma Chapman and Collins, {Ian R.} and O'Reilly, {Rachel K.} and Dove, {Andrew P.}",
year = "2014",
month = apr,
day = "23",
doi = "10.1021/ma500428e",
language = "English",
volume = "47",
pages = "2847--2852",
journal = "Macromolecules",
issn = "0024-9297",
publisher = "American Chemical Society",
number = "9",

}

RIS

TY - JOUR

T1 - Functional Degradable Polymers by Xanthate-Mediated Polymerization

AU - Hedir, Guillaume G.

AU - Bell, Craig A.

AU - Ieong, Nga Sze

AU - Chapman, Emma

AU - Collins, Ian R.

AU - O'Reilly, Rachel K.

AU - Dove, Andrew P.

PY - 2014/4/23

Y1 - 2014/4/23

N2 - Herein we report the first example of the controlled synthesis of linear and hyperbranched copolymers of 2-methylene-1,3-dioxepane (MDO) with functional vinyl monomers to deliver a range of functional, degradable polymers by reversible deactivation radical polymerization. The copolymerization was able to be tuned to vary the incorporation of degradable segments to create degradable materials with predictable molar mass, low dispersity values while also featuring side-chain functionality. The formation of nanoparticles by the addition of divinyladipate to form degradable hyperbranched copolymers was proven by DLS and TEM analyses.

AB - Herein we report the first example of the controlled synthesis of linear and hyperbranched copolymers of 2-methylene-1,3-dioxepane (MDO) with functional vinyl monomers to deliver a range of functional, degradable polymers by reversible deactivation radical polymerization. The copolymerization was able to be tuned to vary the incorporation of degradable segments to create degradable materials with predictable molar mass, low dispersity values while also featuring side-chain functionality. The formation of nanoparticles by the addition of divinyladipate to form degradable hyperbranched copolymers was proven by DLS and TEM analyses.

UR - http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=ORCID&SrcApp=OrcidOrg&DestLinkType=FullRecord&DestApp=WOS_CPL&KeyUT=WOS:000336020900010&KeyUID=WOS:000336020900010

U2 - 10.1021/ma500428e

DO - 10.1021/ma500428e

M3 - Article

VL - 47

SP - 2847

EP - 2852

JO - Macromolecules

JF - Macromolecules

SN - 0024-9297

IS - 9

ER -