Experimental validation of Marcus theory for outer-sphere heterogeneous electron-transfer reactions: The oxidation of substituted 1,4-phenylenediamines

A.D. Clegg; N.V. Rees; O.V. Klymenko; B.A. Coles; R.G. Compton

doi:10.1002/cphc.200400128

Experimental validation of Marcus theory for outer-sphere heterogeneous electron-transfer reactions: The oxidation of substituted 1,4-phenylenediamines

A.D. Clegg, N.V. Rees, O.V. Klymenko, B.A. Coles, R.G. Compton

Chemical Engineering

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

Rate constants depend on molecular size: Results are presented to validate the relationship between molecular size and the standard electrochemical rate constant predicted by Marcus theory (see graphic). Measurement of hydrodynamic radii and electron-transfer rates for substituted 1,4-phenylenediamines have been made under steady-state conditions using both hydrodynamic and stationary electrodes.

Original language	English
Pages (from-to)	1234-1240
Number of pages	7
Journal	ChemPhysChem
Volume	5
Issue number	8
DOIs	https://doi.org/10.1002/cphc.200400128
Publication status	Published - 20 Aug 2004

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abstract = "Rate constants depend on molecular size: Results are presented to validate the relationship between molecular size and the standard electrochemical rate constant predicted by Marcus theory (see graphic). Measurement of hydrodynamic radii and electron-transfer rates for substituted 1,4-phenylenediamines have been made under steady-state conditions using both hydrodynamic and stationary electrodes.",

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AU - Coles, B.A.

AU - Compton, R.G.

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AB - Rate constants depend on molecular size: Results are presented to validate the relationship between molecular size and the standard electrochemical rate constant predicted by Marcus theory (see graphic). Measurement of hydrodynamic radii and electron-transfer rates for substituted 1,4-phenylenediamines have been made under steady-state conditions using both hydrodynamic and stationary electrodes.

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Experimental validation of Marcus theory for outer-sphere heterogeneous electron-transfer reactions: The oxidation of substituted 1,4-phenylenediamines

Abstract

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