TY - JOUR
T1 - Enhanced efficiency and stability of polymer solar cells using solution-processed nickel oxide as hole transport material
AU - Parthiban, Shanmugam
AU - Kim, Seungmin
AU - Tamilavan, Vellaiappillai
AU - Lee, Jihoon
AU - Shin, Insoo
AU - Dhayalan, Yuvaraj
AU - Jung, Yun Kyung
AU - Hyun, Myung Ho
AU - Jeong, Jung Hyun
AU - Park, Sung Heum
PY - 2017/10/1
Y1 - 2017/10/1
N2 - Solution-processed nickel oxide (s-NiOx) was synthesized for use as hole-transport layers (HTLs) in the fabrication of polymer solar cell (PSC) devices. The s-NiOx thin-films were deposited using spin-coating and post-annealed at 300 °C, 400 °C, or 500 °C. With increased annealing temperature, the nickel acetate precursor decomposes more fully and forms s-NiOx films that show larger crystalline grain sizes with lower root mean square surface roughness. Bulk heterojunction solar cells fabricated with the new random polymer RP(BDT-PDBT) and [6,6]-phenyl-C70-butyric acid methyl ester (PC70BM) using s-NiOx as HTLs exhibit a 4.46% enhancement in power conversion efficiency and better stability compared to conventional PSCs using poly (3,4-ethylenedioxythiophene):poly(styrene sulfonate) as HTLs. We believe that the solution-processable and highly stable s-NiOx could be a potential alternative for functional interface materials in optoelectronic devices.
AB - Solution-processed nickel oxide (s-NiOx) was synthesized for use as hole-transport layers (HTLs) in the fabrication of polymer solar cell (PSC) devices. The s-NiOx thin-films were deposited using spin-coating and post-annealed at 300 °C, 400 °C, or 500 °C. With increased annealing temperature, the nickel acetate precursor decomposes more fully and forms s-NiOx films that show larger crystalline grain sizes with lower root mean square surface roughness. Bulk heterojunction solar cells fabricated with the new random polymer RP(BDT-PDBT) and [6,6]-phenyl-C70-butyric acid methyl ester (PC70BM) using s-NiOx as HTLs exhibit a 4.46% enhancement in power conversion efficiency and better stability compared to conventional PSCs using poly (3,4-ethylenedioxythiophene):poly(styrene sulfonate) as HTLs. We believe that the solution-processable and highly stable s-NiOx could be a potential alternative for functional interface materials in optoelectronic devices.
KW - Polymer solar cell
KW - Hole transport layer
KW - Nickel oxide
U2 - 10.1016/j.cap.2017.06.002
DO - 10.1016/j.cap.2017.06.002
M3 - Article
SN - 1567-1739
VL - 17
SP - 1232
EP - 1237
JO - Current Applied Physics
JF - Current Applied Physics
IS - 10
ER -