Double Layered CeO2-Co3O4-CuO Based Anode for Direct Utilisation of Methane or Ethanol in SOFC

Bernardo Sarruf; Jong-Eun Hong; Robert Steinberger-Wilckens; Paulo Emilio Miranda

doi:10.1149/07801.1343ecst

Double Layered CeO2-Co3O4-CuO Based Anode for Direct Utilisation of Methane or Ethanol in SOFC

Bernardo Sarruf, Jong-Eun Hong, Robert Steinberger-Wilckens, Paulo Emilio Miranda

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

242 Downloads (Pure)

Abstract

The present work aims at producing an electrocatalyst suitable to be used as anode in solid oxide fuel cells that operate with hydrocarbons or alcohols as fuel. The main challenge is to avoid carbon deposition during operation with carbonaceous fuels. Therefore, a cerium-cobalt-copper anode was developed, characterised and tested with methane or ethanol fuel, resulting in reasonable power densities and no evidence of carbon deposition as confirmed by Raman spectroscopy. SEM/EDX analysis showed the integrity of anode microstructure and phase distribution after the ageing procedure.

Original language	English
Title of host publication	Proceedings of the 15th International Symposium on Solid Oxide Fuel Cells (SOFC-XV)
Editors	Subhash Singhal
Publisher	Electrochemical Society Inc.
Number of pages	9
DOIs	https://doi.org/10.1149/07801.1343ecst
Publication status	Published - 23 Jul 2017
Event	15th International Symposium on Solid Oxide Fuel Cells, SOFC, 2017 - Hollywood, FL, U.S.A., Hollywood, United States Duration: 23 Jul 2017 → 28 Jul 2017 http://www.electrochem.org/sofc-xv

Conference

Conference	15th International Symposium on Solid Oxide Fuel Cells, SOFC, 2017
Abbreviated title	SOFC XV
Country/Territory	United States
City	Hollywood
Period	23/07/17 → 28/07/17
Internet address	http://www.electrochem.org/sofc-xv

Keywords

SOFC
SOFC anode
Ethanol
Methane reforming
Carbon deposition

ASJC Scopus subject areas

Fuel Technology
Process Chemistry and Technology
Catalysis
Energy(all)

Access to Document

10.1149/07801.1343ecst

BernardoSarruf SOFC-XV_final
Copyright 2017, The Electrochemical Society.
Accepted author manuscript, 1.78 MBLicence: None: All rights reserved

Cite this

@inproceedings{93f201819b66424b91094443eda162a4,

title = "Double Layered CeO2-Co3O4-CuO Based Anode for Direct Utilisation of Methane or Ethanol in SOFC",

abstract = "The present work aims at producing an electrocatalyst suitable to be used as anode in solid oxide fuel cells that operate with hydrocarbons or alcohols as fuel. The main challenge is to avoid carbon deposition during operation with carbonaceous fuels. Therefore, a cerium-cobalt-copper anode was developed, characterised and tested with methane or ethanol fuel, resulting in reasonable power densities and no evidence of carbon deposition as confirmed by Raman spectroscopy. SEM/EDX analysis showed the integrity of anode microstructure and phase distribution after the ageing procedure.",

keywords = "SOFC, SOFC anode, Ethanol, Methane reforming, Carbon deposition",

author = "Bernardo Sarruf and Jong-Eun Hong and Robert Steinberger-Wilckens and Miranda, {Paulo Emilio}",

year = "2017",

month = jul,

day = "23",

doi = "10.1149/07801.1343ecst",

language = "English",

editor = "Subhash Singhal",

booktitle = "Proceedings of the 15th International Symposium on Solid Oxide Fuel Cells (SOFC-XV)",

publisher = "Electrochemical Society Inc.",

address = "United States",

note = "15th International Symposium on Solid Oxide Fuel Cells, SOFC, 2017, SOFC XV ; Conference date: 23-07-2017 Through 28-07-2017",

url = "http://www.electrochem.org/sofc-xv",

}

Sarruf, B, Hong, J-E, Steinberger-Wilckens, R & Miranda, PE 2017, Double Layered CeO2-Co3O4-CuO Based Anode for Direct Utilisation of Methane or Ethanol in SOFC. in S Singhal (ed.), Proceedings of the 15th International Symposium on Solid Oxide Fuel Cells (SOFC-XV). Electrochemical Society Inc., 15th International Symposium on Solid Oxide Fuel Cells, SOFC, 2017, Hollywood, United States, 23/07/17. https://doi.org/10.1149/07801.1343ecst

Double Layered CeO2-Co3O4-CuO Based Anode for Direct Utilisation of Methane or Ethanol in SOFC. / Sarruf, Bernardo; Hong, Jong-Eun; Steinberger-Wilckens, Robert et al.
Proceedings of the 15th International Symposium on Solid Oxide Fuel Cells (SOFC-XV). ed. / Subhash Singhal. Electrochemical Society Inc., 2017.

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

TY - GEN

T1 - Double Layered CeO2-Co3O4-CuO Based Anode for Direct Utilisation of Methane or Ethanol in SOFC

AU - Sarruf, Bernardo

AU - Hong, Jong-Eun

AU - Steinberger-Wilckens, Robert

AU - Miranda, Paulo Emilio

PY - 2017/7/23

Y1 - 2017/7/23

N2 - The present work aims at producing an electrocatalyst suitable to be used as anode in solid oxide fuel cells that operate with hydrocarbons or alcohols as fuel. The main challenge is to avoid carbon deposition during operation with carbonaceous fuels. Therefore, a cerium-cobalt-copper anode was developed, characterised and tested with methane or ethanol fuel, resulting in reasonable power densities and no evidence of carbon deposition as confirmed by Raman spectroscopy. SEM/EDX analysis showed the integrity of anode microstructure and phase distribution after the ageing procedure.

AB - The present work aims at producing an electrocatalyst suitable to be used as anode in solid oxide fuel cells that operate with hydrocarbons or alcohols as fuel. The main challenge is to avoid carbon deposition during operation with carbonaceous fuels. Therefore, a cerium-cobalt-copper anode was developed, characterised and tested with methane or ethanol fuel, resulting in reasonable power densities and no evidence of carbon deposition as confirmed by Raman spectroscopy. SEM/EDX analysis showed the integrity of anode microstructure and phase distribution after the ageing procedure.

KW - SOFC

KW - SOFC anode

KW - Ethanol

KW - Methane reforming

KW - Carbon deposition

U2 - 10.1149/07801.1343ecst

DO - 10.1149/07801.1343ecst

M3 - Conference contribution

BT - Proceedings of the 15th International Symposium on Solid Oxide Fuel Cells (SOFC-XV)

A2 - Singhal, Subhash

PB - Electrochemical Society Inc.

T2 - 15th International Symposium on Solid Oxide Fuel Cells, SOFC, 2017

Y2 - 23 July 2017 through 28 July 2017

ER -

Double Layered CeO2-Co3O4-CuO Based Anode for Direct Utilisation of Methane or Ethanol in SOFC

Abstract

Conference

Keywords

ASJC Scopus subject areas

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