Designing a facile low cost synthesis strategy for the Na-V-S-O systems, NaV(SO4)2, Na3V(SO4)3 and Na2VO(SO4)2

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@article{6a9858c1c08943968ccddf245cf30775,
title = "Designing a facile low cost synthesis strategy for the Na-V-S-O systems, NaV(SO4)2, Na3V(SO4)3 and Na2VO(SO4)2",
abstract = "Alkali metal transition metal sulfates have attracted considerable interest as potential electrodes for Na ion battery materials. While there has been significant research on Fe based systems, research on V based systems has been lacking, apart from a recent report on Na2VO(SO4)2. This can be related to the complex synthetic routes previously reported to make sodium vanadium sulfate systems. In this paper, we report a simple route towards the synthesis of three such sodium vanadium sulfate systems, NaV(SO4)2, Na2VO(SO4)2, and Na3V(SO4)3. We analyse the resulting products through X-ray diffraction and Raman spectroscopy to highlight the formation of high quality samples via this simple solution route, with subsequent low temperature (<400 °C) heat treatment. This facile new route will allow these materials to be considered for future applications rather than as simply chemical curiosities.",
author = "Laura Driscoll and Adrian Wright and Peter Slater",
year = "2018",
month = oct
day = "14",
doi = "10.1039/C8DT02308E",
language = "English",
volume = "47",
pages = "13535--13542 ",
journal = "Dalton Transactions",
issn = "1477-9234",
publisher = "Royal Society of Chemistry",
number = "38",

}

RIS

TY - JOUR

T1 - Designing a facile low cost synthesis strategy for the Na-V-S-O systems, NaV(SO4)2, Na3V(SO4)3 and Na2VO(SO4)2

AU - Driscoll, Laura

AU - Wright, Adrian

AU - Slater, Peter

PY - 2018/10/14

Y1 - 2018/10/14

N2 - Alkali metal transition metal sulfates have attracted considerable interest as potential electrodes for Na ion battery materials. While there has been significant research on Fe based systems, research on V based systems has been lacking, apart from a recent report on Na2VO(SO4)2. This can be related to the complex synthetic routes previously reported to make sodium vanadium sulfate systems. In this paper, we report a simple route towards the synthesis of three such sodium vanadium sulfate systems, NaV(SO4)2, Na2VO(SO4)2, and Na3V(SO4)3. We analyse the resulting products through X-ray diffraction and Raman spectroscopy to highlight the formation of high quality samples via this simple solution route, with subsequent low temperature (<400 °C) heat treatment. This facile new route will allow these materials to be considered for future applications rather than as simply chemical curiosities.

AB - Alkali metal transition metal sulfates have attracted considerable interest as potential electrodes for Na ion battery materials. While there has been significant research on Fe based systems, research on V based systems has been lacking, apart from a recent report on Na2VO(SO4)2. This can be related to the complex synthetic routes previously reported to make sodium vanadium sulfate systems. In this paper, we report a simple route towards the synthesis of three such sodium vanadium sulfate systems, NaV(SO4)2, Na2VO(SO4)2, and Na3V(SO4)3. We analyse the resulting products through X-ray diffraction and Raman spectroscopy to highlight the formation of high quality samples via this simple solution route, with subsequent low temperature (<400 °C) heat treatment. This facile new route will allow these materials to be considered for future applications rather than as simply chemical curiosities.

U2 - 10.1039/C8DT02308E

DO - 10.1039/C8DT02308E

M3 - Article

C2 - 30204185

VL - 47

SP - 13535

EP - 13542

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9234

IS - 38

ER -