TY - JOUR
T1 - Copper(I) complexes as alternatives to iridium(III) complexes for highly efficient oxygen sensing
AU - Medina-Rodríguez, Santiago
AU - Orriach-Fernández, Francisco J
AU - Poole, Christopher
AU - Kumar, Prashant
AU - de la Torre-Vega, Ángel
AU - Fernández-Sánchez, Jorge F
AU - Baranoff, Etienne
AU - Fernández-Gutiérrez, Alberto
PY - 2015/7/21
Y1 - 2015/7/21
N2 - The complex [Cu(xantphos)(dmp)][PF6] (dmp = 2,9-dimethyl-1,10-phenanthroline) in a nanostructured metal oxyde matrix shows better sensitivity to oxygen (KSV = 9.74 ± 0.87 kPa(-1) between 0 and 1 kPa pO2 and 5.59 ± 0.15 kPa(-1) between 0 and 10 kPa pO2) than cyclometallated iridium complexes in the same conditions.
AB - The complex [Cu(xantphos)(dmp)][PF6] (dmp = 2,9-dimethyl-1,10-phenanthroline) in a nanostructured metal oxyde matrix shows better sensitivity to oxygen (KSV = 9.74 ± 0.87 kPa(-1) between 0 and 1 kPa pO2 and 5.59 ± 0.15 kPa(-1) between 0 and 10 kPa pO2) than cyclometallated iridium complexes in the same conditions.
U2 - 10.1039/c5cc04326c
DO - 10.1039/c5cc04326c
M3 - Article
C2 - 26086848
SN - 1359-7345
VL - 51
SP - 11401
EP - 11404
JO - Chemical Communications
JF - Chemical Communications
IS - 57
ER -