Characterisation of undoped and doped isomeric o,m,p-polyphenylenes by -X-Ray, FTIR and electrical conductivity measurements

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Characterisation of undoped and doped isomeric o,m,p-polyphenylenes by -X-Ray, FTIR and electrical conductivity measurements. / Simitzis, Johannes ; Stamboulis, Artemis; Hinrichsen, Georg.

In: International Journal of Polymer Analysis and Characterisation, Vol. 1, No. 3, 01.11.1995, p. 175-183.

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@article{50743b47e1bd4bed901f13f80a575691,
title = "Characterisation of undoped and doped isomeric o,m,p-polyphenylenes by -X-Ray, FTIR and electrical conductivity measurements",
abstract = "Isomeric o, m, p-polyphenylenes were prepared by oxidation-cationic polymeriation of biphenyl with various proportions of the polymerization components biphenyl-AlCl3-Cu-Cl2. The insoluble fraction in chlorobenzene was separated. The insoluble polyphenylenes were then doped with anhydrous FeCl3, AlCl3, and SnCl4 in solutions of acetonitrile (ACN), nitrobenzene (N), and acetone (A). X-ray diffraction, Fourier Transform Infrared Spectroscopy (FTIR), and electrical conductivity measurements were carried out to characterize the undoped and doped materials. Some of the o, m, p-polyphenylenes had semiconductive properties after doping depending on the proportion of biphenyl-AlCl3-CuCl2 and the doping system (dopant and solvent).",
keywords = "Doping, Electrical conductive polymers, Polyphenylenes",
author = "Johannes Simitzis and Artemis Stamboulis and Georg Hinrichsen",
note = "Funding Information: The authors would like to thank the German-Greek Committee on Science and Technology for the financial support of the corresponding project “Semiconductive Organic Polymers.”",
year = "1995",
month = nov,
day = "1",
doi = "10.1080/10236669508233872",
language = "English",
volume = "1",
pages = "175--183",
journal = "International Journal of Polymer Analysis and Characterisation",
issn = "1023-666X",
publisher = "Taylor & Francis",
number = "3",

}

RIS

TY - JOUR

T1 - Characterisation of undoped and doped isomeric o,m,p-polyphenylenes by -X-Ray, FTIR and electrical conductivity measurements

AU - Simitzis, Johannes

AU - Stamboulis, Artemis

AU - Hinrichsen, Georg

N1 - Funding Information: The authors would like to thank the German-Greek Committee on Science and Technology for the financial support of the corresponding project “Semiconductive Organic Polymers.”

PY - 1995/11/1

Y1 - 1995/11/1

N2 - Isomeric o, m, p-polyphenylenes were prepared by oxidation-cationic polymeriation of biphenyl with various proportions of the polymerization components biphenyl-AlCl3-Cu-Cl2. The insoluble fraction in chlorobenzene was separated. The insoluble polyphenylenes were then doped with anhydrous FeCl3, AlCl3, and SnCl4 in solutions of acetonitrile (ACN), nitrobenzene (N), and acetone (A). X-ray diffraction, Fourier Transform Infrared Spectroscopy (FTIR), and electrical conductivity measurements were carried out to characterize the undoped and doped materials. Some of the o, m, p-polyphenylenes had semiconductive properties after doping depending on the proportion of biphenyl-AlCl3-CuCl2 and the doping system (dopant and solvent).

AB - Isomeric o, m, p-polyphenylenes were prepared by oxidation-cationic polymeriation of biphenyl with various proportions of the polymerization components biphenyl-AlCl3-Cu-Cl2. The insoluble fraction in chlorobenzene was separated. The insoluble polyphenylenes were then doped with anhydrous FeCl3, AlCl3, and SnCl4 in solutions of acetonitrile (ACN), nitrobenzene (N), and acetone (A). X-ray diffraction, Fourier Transform Infrared Spectroscopy (FTIR), and electrical conductivity measurements were carried out to characterize the undoped and doped materials. Some of the o, m, p-polyphenylenes had semiconductive properties after doping depending on the proportion of biphenyl-AlCl3-CuCl2 and the doping system (dopant and solvent).

KW - Doping

KW - Electrical conductive polymers

KW - Polyphenylenes

UR - http://www.scopus.com/inward/record.url?scp=84956375915&partnerID=8YFLogxK

U2 - 10.1080/10236669508233872

DO - 10.1080/10236669508233872

M3 - Article

AN - SCOPUS:84956375915

VL - 1

SP - 175

EP - 183

JO - International Journal of Polymer Analysis and Characterisation

JF - International Journal of Polymer Analysis and Characterisation

SN - 1023-666X

IS - 3

ER -